Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction
	Guo, Xiaoling 1,2; Qi, Wei 2; Liu, Wei 2; Liang, Changhai 1; Zheng, Anmin 3; Yi, Xianfeng 3; Su, Dangsheng 2
刊名	RSC ADVANCES
	2016
卷号	6 期号:101 页码:99570-99576
英文摘要	A series of conjugated polymers (YPB-x) with designated chemical structure are synthesized as model carbon catalysts for mechanistic and kinetic studies of nitroaromatic reduction reactions. The reaction kinetics show that ketonic carbonyl groups are active sites for the nitrobenzene (NB) reduction. A catalytic reaction mechanism involving the activation of hydrazine with carbon catalysts and the subsequent reduction of NB is proposed to describe the catalytic process molecularly. The turnover frequency of heterogeneous carbon catalysts in the liquid phase is reported for the fair comparison of the intrinsic activity among different carbon catalysts.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	OXIDATIVE DEHYDROGENATION ; HETEROGENEOUS CATALYST ; NITROBENZENE ; HYDROGENATION ; POLYMERIZATION ; CARBOCATALYSIS ; ETHYLBENZENE ; NANOCARBON ; HYDRAZINE ; CHEMISTRY
收录类别	SCI
语种	英语
WOS记录号	WOS:000387427800121
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/9969]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Guo, Xiaoling,Qi, Wei,Liu, Wei,et al. Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction[J]. RSC ADVANCES,2016,6(101):99570-99576.
APA	Guo, Xiaoling.,Qi, Wei.,Liu, Wei.,Liang, Changhai.,Zheng, Anmin.,...&Su, Dangsheng.(2016).Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction.RSC ADVANCES,6(101),99570-99576.
MLA	Guo, Xiaoling,et al."Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction".RSC ADVANCES 6.101(2016):99570-99576.