Synthesis of ketones from biomass-derived feedstock

CORC > 化学研究所 > 中国科学院化学研究所 > 胶体、界面与化学热力学实验室

	Synthesis of ketones from biomass-derived feedstock
	Meng, Qinglei 1; Hou, Minqiang 1; Liu, Huizhen 1,2; Song, Jinliang 1; Han, Buxing 1,2
刊名	Nature Communications
	2017-01-31
卷号	8
英文摘要	Cyclohexanone and its derivatives are very important chemicals, which are currently produced mainly by oxidation of cyclohexane or alkylcyclohexane, hydrogenation of phenols, and alkylation of cyclohexanone. Here we report that bromide salt-modified Pd/C in H2O/CH2Cl2 can efficiently catalyse the transformation of aromatic ethers, which can be derived from biomass, to cyclohexanone and its derivatives via hydrogenation and hydrolysis processes. The yield of cyclohexanone from anisole can reach 96%, and the yields of cyclohexanone derivatives produced from the aromatic ethers, which can be extracted from plants or derived from lignin, are also satisfactory. Detailed study shows that the Pd, bromide salt and H2O/CH2Cl2 work cooperatively to promote the desired reaction and inhibit the side reaction. Thus high yields of desired products can be obtained. This work opens the way for production of ketones from aromatic ethers that can be derived from biomass.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/36540]
专题	化学研究所_胶体、界面与化学热力学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid & Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Meng, Qinglei,Hou, Minqiang,Liu, Huizhen,et al. Synthesis of ketones from biomass-derived feedstock[J]. Nature Communications,2017,8.
APA	Meng, Qinglei,Hou, Minqiang,Liu, Huizhen,Song, Jinliang,&Han, Buxing.(2017).Synthesis of ketones from biomass-derived feedstock.Nature Communications,8.
MLA	Meng, Qinglei,et al."Synthesis of ketones from biomass-derived feedstock".Nature Communications 8(2017).