Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters
Li JW(李加文)1,3; Qin GP(秦贵平)1,3; Huang HM(黄汉民)1,2
刊名Organic and Biomolecular Chemistry
2016
卷号14期号:45页码:10572-10575
ISSN号1477-0520
通讯作者黄汉民
英文摘要

A novel silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate producing β-amino-α-diazoesters has been developed. A series of aminals with different amino moieties and substituents were successfully incorporated in this reaction, which delivered a wide range of β-amino-α-diazocarbonyl compounds in the presence of a lower catalyst loading in 2 hours.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the CAS Interdisciplinary Innovation Team;the National Natural Science Foundation of China (21133011;21672199)
语种英语
WOS记录号WOS:000388923600004
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/21203]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li JW,Qin GP,Huang HM. Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters[J]. Organic and Biomolecular Chemistry,2016,14(45):10572-10575.
APA Li JW,Qin GP,&Huang HM.(2016).Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters.Organic and Biomolecular Chemistry,14(45),10572-10575.
MLA Li JW,et al."Silver-catalyzed nucleophilic substitution of aminals with ethyl diazoacetate: a new pathway to beta-amino-alpha-diazoesters".Organic and Biomolecular Chemistry 14.45(2016):10572-10575.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace