Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes
Yu W(余伟)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
刊名Adv. Synth. Catal.
2015
卷号357期号:9页码:2039-2044
其他题名银参与未活化烯烃的氧化三氟甲基化反应
通讯作者卿凤翎
英文摘要An efficient regioselective fluorotrifluoro-methylation of unactivated alkenes has been developed. The reaction of alkenes with (trifluoromethyl) trimethylsilane (TMSCF3) and Selectfluor in the presence of silver trifluoromethanesulfonate (AgOTf), cesium fluoride (CsF), and iodobenzene diacetate [PhI(OAc)(2)] in N,N-dimethylformamide (DMF) at -20 degrees C gave the corresponding fluorotrifluoromethylated products in moderate to good yields. The silver salt turns out to be crucial for this transformation.
学科主题氟化学
收录类别SCI
原文出处http://dx.doi.org/10.1002/adsc.201500027
语种英语
WOS记录号WOS:000356373200008
内容类型期刊论文
源URL[http://ir.sioc.ac.cn/handle/331003/39728]  
专题上海有机化学研究所_中科院有机氟化学重点实验室
作者单位1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学
推荐引用方式
GB/T 7714
Yu W,Xu XH,Qing FL. Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes[J]. Adv. Synth. Catal.,2015,357(9):2039-2044.
APA 余伟,徐修华,&卿凤翎.(2015).Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes.Adv. Synth. Catal.,357(9),2039-2044.
MLA 余伟,et al."Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes".Adv. Synth. Catal. 357.9(2015):2039-2044.
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