Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols | |
Zhang JS(张加生)1; Ye JT(叶俊涛)1; Ma SM(麻生明)1 | |
刊名 | Org. Biomol. Chem.
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2015 | |
卷号 | 13期号:13页码:4080-4089 |
其他题名 | CdI2和CuBr共催化的一锅法合成光学活性的α-联烯醇的方法 |
通讯作者 | 麻生明 |
英文摘要 | A highly efficient one-pot synthesis of chiral alpha-allenols from propargylic alcohols, aldehydes and pyrrolidine induced by CuBr and (R,R-a)-N-PINAP or (R,S-a)-N-PINAP and CdI2 has been developed. Both the yields and enantioselectivities of the allenols of this one-pot procedure are practical. Comparison with ZnI2 control experiments revealed that CdI2 can convert propargylic amine to allene in the presence of CuBr efficiently. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c4ob02673j |
语种 | 英语 |
WOS记录号 | WOS:000351597700028 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39589] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.复旦大学 |
推荐引用方式 GB/T 7714 | Zhang JS,Ye JT,Ma SM. Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols[J]. Org. Biomol. Chem.,2015,13(13):4080-4089. |
APA | 张加生,叶俊涛,&麻生明.(2015).Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols.Org. Biomol. Chem.,13(13),4080-4089. |
MLA | 张加生,et al."Harmony of CdI2 with CuBr for the one-pot synthesis of optically active alpha-allenols".Org. Biomol. Chem. 13.13(2015):4080-4089. |
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