Simultaneous and selective transformation of glucose to arabinose and nitrosobenzene to azoxybenzene driven by visible-light

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	Simultaneous and selective transformation of glucose to arabinose and nitrosobenzene to azoxybenzene driven by visible-light
	Zhou, Baowen; Song, Jinliang; Wu, Tianbin; Liu, Huizhen; Xie, Chao; Yang, Guanying; Han, Buxing
刊名	GREEN CHEMISTRY
	2016
卷号	18 期号:13 页码:3852-3857
英文摘要	Both the selective conversion of glucose into arabinose and the reduction of nitrosobenzene to azoxybenzene are very important but challenging processes. Herein we carried out the first work on the simultaneous transformation of glucose to arabinose and of nitrosobenzene to azoxybenzene by photocatalysis. It was found that Pd nanoparticles supported on mesoporous CdS were very active and selective for the reactions in water under visible light irradiation. Nitrosobenzene could be reduced to azoxybenzene with a selectivity of 92% by hydrogen from water and glucose. More importantly, glucose was oxidized to arabinose with high selectivity (70%) by photoexcited holes. The reaction mechanism and the reason for the high selectivity were studied using control experiments.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35607]
专题	化学研究所_胶体、界面与化学热力学实验室
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Baowen,Song, Jinliang,Wu, Tianbin,et al. Simultaneous and selective transformation of glucose to arabinose and nitrosobenzene to azoxybenzene driven by visible-light[J]. GREEN CHEMISTRY,2016,18(13):3852-3857.
APA	Zhou, Baowen.,Song, Jinliang.,Wu, Tianbin.,Liu, Huizhen.,Xie, Chao.,...&Han, Buxing.(2016).Simultaneous and selective transformation of glucose to arabinose and nitrosobenzene to azoxybenzene driven by visible-light.GREEN CHEMISTRY,18(13),3852-3857.
MLA	Zhou, Baowen,et al."Simultaneous and selective transformation of glucose to arabinose and nitrosobenzene to azoxybenzene driven by visible-light".GREEN CHEMISTRY 18.13(2016):3852-3857.