A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response
	Li, L (Li, Lin); Wang, Y (Wang, Ying); Lei, BH (Lei, Bing-Hua); Han, SJ (Han, Shujuan); Yang, ZH (Yang, Zhihua); Poeppelmeier, KR (Poeppelmeier, Kenneth R.); Pan, SL (Pan, Shilie)
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2016
卷号	138 期号:29 页码:9101-9104
通讯作者	Pan, SL
英文摘要	LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very short absorption edge of A = 174 nm and generates the largest powder second harmonic generation (SHG) response for deep-UV phosphates that do not contain additional anionic groups, i.e., 2.6 times that of KH2PO4 (KDP). First-principles electronic structure analyses confirm the experimental results and suggest that the strong SHG response may originate from the aligned nonbonding O-2p orbitals. The discovery and characterization of LiCs2PO4 provide a new insight into the structure property relationships of phosphate-based nonlinear optical materials with large SHG responses and short absorption edges.
收录类别	SCI
WOS记录号	WOS:000380730000028
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4647]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
推荐引用方式 GB/T 7714	Li, L ,Wang, Y ,Lei, BH ,et al. A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016,138(29):9101-9104.
APA	Li, L .,Wang, Y .,Lei, BH .,Han, SJ .,Yang, ZH .,...&Pan, SL .(2016).A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,138(29),9101-9104.
MLA	Li, L ,et al."A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138.29(2016):9101-9104.