Nickel(II) and copper(II) complexes containing 2-(2-(5-substitued isoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione ligands: Synthesis, spectral and thermal characterizations

CORC > 上海光学精密机械研究所 > 中国科学院上海光学精密机械研究所 > 高密度光存储技术实验室

	Nickel(II) and copper(II) complexes containing 2-(2-(5-substitued isoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione ligands: Synthesis, spectral and thermal characterizations
	Chen ZM(陈志敏) ; Wu YQ(吴谊群) ; Gu DH(顾冬红) ; Gan FX(干福熹)
刊名	dyes pigment.
	2008
卷号	76 期号:3 页码:624
关键词	hydrazones metal(II) complexes spin-coating film absorption spectra thermal property
ISSN号	0143-7208
中文摘要	two new hydrazone chelating ligands, 2-(2-(5-methylisoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione (hl1) and 2-(2-(5-tert-butylisoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane- 1,3-dione (hl2), and their nickel(ii) and copper(ii) complexes were synthesized using the procedure of diazotization, coupling and metallization. their structures were postulated based on elemental analysis, h-1 nmr, esi-ms, ft-ir spectra and uv-vis electronic absorption spectra. smooth films of these complexes on k9 glass substrates were prepared using spin-coating and their absorption properties were evaluated. the thermal properties of the metal(ii) complexes were investigated by thermogravimetry (tg) and differential thermogravimetry (dtg). different thermodynamic and kinetic parameters namely activation energy (e
学科主题	光存储
收录类别	EI
语种	norwegian
WOS记录号	WOS:000250223300007
公开日期	2009-09-22
内容类型	期刊论文
源URL	[http://ir.siom.ac.cn/handle/181231/4065]
专题	上海光学精密机械研究所_高密度光存储技术实验室
推荐引用方式 GB/T 7714	Chen ZM,Wu YQ,Gu DH,et al. Nickel(II) and copper(II) complexes containing 2-(2-(5-substitued isoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione ligands: Synthesis, spectral and thermal characterizations[J]. dyes pigment.,2008,76(3):624, 631.
APA	陈志敏,吴谊群,顾冬红,&干福熹.(2008).Nickel(II) and copper(II) complexes containing 2-(2-(5-substitued isoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione ligands: Synthesis, spectral and thermal characterizations.dyes pigment.,76(3),624.
MLA	陈志敏,et al."Nickel(II) and copper(II) complexes containing 2-(2-(5-substitued isoxazol-3-yl)hydrazono)-5,5-dimethylcyclohexane-1,3-dione ligands: Synthesis, spectral and thermal characterizations".dyes pigment. 76.3(2008):624.