Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds | |
Liu, Jianzhong; Xie, Ying; Zeng, Wei; Lin, Dongen; Deng, Yuanfu; Lu, Xiaoxia | |
刊名 | JOURNAL OF ORGANIC CHEMISTRY |
2015 | |
卷号 | 80期号:9页码:4618-4626 |
关键词 | C-H BONDS PALLADIUM-CATALYZED ARYLATION C(SP(3))-H BONDS INTERMOLECULAR ARYLATION SELECTIVE ALKENYLATION ACTIVATION ACIDS AUXILIARY COPPER SP(2) |
通讯作者 | Zeng, W (reprint author), S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China. |
产权排序 | 1 |
合作状况 | 国内 |
英文摘要 | A novel Pd(II)-catalyzed pyridine hi-oxide directed remote arylation of unactivated C-sp(3)-H bonds in aliphatic amides with aryl iodides has been developed. This protocol allows installing various aryl groups at the beta, or gamma-C-sp(3) atom of alkyl carboxylic acid amides. The key palladabicyclic intermediate of this transformation has been identified by HR-MS and H-1 NMR method. |
学科主题 | Chemistry |
类目[WOS] | Chemistry, Organic |
收录类别 | SCI |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://210.75.237.14/handle/351003/27586] |
专题 | 成都生物研究所_天然产物研究 |
推荐引用方式 GB/T 7714 | Liu, Jianzhong,Xie, Ying,Zeng, Wei,et al. Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds[J]. JOURNAL OF ORGANIC CHEMISTRY,2015,80(9):4618-4626. |
APA | Liu, Jianzhong,Xie, Ying,Zeng, Wei,Lin, Dongen,Deng, Yuanfu,&Lu, Xiaoxia.(2015).Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds.JOURNAL OF ORGANIC CHEMISTRY,80(9),4618-4626. |
MLA | Liu, Jianzhong,et al."Pd(II)-Catalyzed Pyridine N-Oxides Directed Arylation of Unactivated C-sp(3)-H Bonds".JOURNAL OF ORGANIC CHEMISTRY 80.9(2015):4618-4626. |
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