New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021

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	New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021
	Sun, Yu-Lin; Zhang, Xiao-Yong; Nong, Xu-Hua; Xu, Xin-Ya; Qi, Shu-Hua
刊名	TETRAHEDRON LETTERS
	2016
卷号	57 期号:3 页码:366-370
关键词	Deep-sea-derived fungus Trichobotrys effuse Macrodiolide Trichobotrysides A-C Absolute configuration Antifouling
通讯作者	Qi, SH (reprint author), Chinese Acad Sci, Key Lab Marine Bioresources Sustainable Utilizat, Guangdong Key Lab Marine Mat Med, RNAM Ctr Marine Microbiol,South China Sea Inst Oc, 164 West Xingang Rd, Guangzhou 510301, Guangdong, Peoples R China.
中文摘要	A new symmetric 16-membered macrodiolide, trichobotryside A (1), and two new asymmetric 18-membered macrodiolides trichobotrysides B-C (2-3) were obtained from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021. Their structures were elucidated by extensive spectroscopic analysis. The absolute configurations of 1 and 2 were established by the methanolysis and modified Mosher method. And the methanolysis of both 1 and 2 produced the new compound of 4R,7S,9S-trihydroxyl-2en-1-methyl decanoate (4). It was rare to obtain an 18-membered macrodiolide from nature. Compound 1 showed strong antifouling activity against Bugula neritina and Balanus amphitrite larvae settlement. (C) 2015 Elsevier Ltd. All rights reserved.
学科主题	Chemistry
内容类型	期刊论文
源URL	[http://ir.scsio.ac.cn/handle/344004/15505]
专题	南海海洋研究所_中科院海洋生物资源可持续利用重点实验室
推荐引用方式 GB/T 7714	Sun, Yu-Lin,Zhang, Xiao-Yong,Nong, Xu-Hua,et al. New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021[J]. TETRAHEDRON LETTERS,2016,57(3):366-370.
APA	Sun, Yu-Lin,Zhang, Xiao-Yong,Nong, Xu-Hua,Xu, Xin-Ya,&Qi, Shu-Hua.(2016).New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021.TETRAHEDRON LETTERS,57(3),366-370.
MLA	Sun, Yu-Lin,et al."New antifouling macrodiolides from the deep-sea-derived fungus Trichobotrys effuse DFFSCS021".TETRAHEDRON LETTERS 57.3(2016):366-370.