Intermediate Role of Gallium in Oxidic Glasses: Solid State NMR Structural Studies of the Ga2O3-NaPO3 System

CORC > 上海光学精密机械研究所 > 中国科学院上海光学精密机械研究所 > 中科院强激光材料重点实验室

	Intermediate Role of Gallium in Oxidic Glasses: Solid State NMR Structural Studies of the Ga2O3-NaPO3 System
	Ren, Jinjun ; Eckert, Hellmut
刊名	j. phys. chem. c
	2014
卷号	118 期号:28 页码:15386
关键词	PHOSPHATE-BASED GLASSES DOUBLE-RESONANCE NMR ALUMINUM METAPHOSPHATE GLASSES MEDIUM-RANGE ORDER QUADRUPOLAR NUCLEI DISORDERED SOLIDS MAS-NMR VIBRATIONAL SPECTROSCOPY RAMAN-SPECTROSCOPY MULTISPIN SYSTEMS
通讯作者	eckert, h (reprint author), univ munster, inst phys chem, corrensstr 30, d-48149 munster, germany.
英文摘要	a series of (napo3)(1-x)(ga2o3)(x) glasses (0 <= x <= 0.35) prepared by conventional melt-quenching methods has been structurally characterized by various complementary high resolution one-dimensional and two-dimensional (2d) solid state magic angle spinning nuclear magnetic resonance (mas nmr) techniques, which were validated by corresponding experiments on the crystalline model compounds gapo4 (quartz) and ga(po3)(3). alloying napo3 glass by ga2o3 results in a marked increase in the glass transition temperature, similar to the effect observed with al2o3. at the atomic level, multiple phosphate species q(mga)(n) (n = 0, 1, and 2; m = 0, 1, 2, and 3) can be observed. here n denotes the number of p-o-p and m the number of p-o-ga linkages, and (m + n <= 4). for resolved resonances, the value of n can be quantified by 2d j-resolved spectroscopy, refocused inadequate, and a recently developed homonuclear dipolar recoupling method termed dq-drenar (double-quantum based dipolar recoupling effects nuclear alignment reduction). ga3+ is dominantly found in six-coordination in low-ga glasses, whereas in glasses with x > 0.15, lower-coordinated ga environments are increasingly favored. the connectivity between p and ga can be assessed by heteronuclear ga-71/p-31 dipolar recoupling experiments using ga-71{p-31} rotational echo double resonance (redor) and p-31 {ga-71} rotational echo adiabatic passage double resonance (readpor) techniques. up to x = 0.25, the limiting composition where this is possible, the second coordination sphere of all the gallium atoms is fully dominated by phosphorus atoms. above x = 0.25, ga-71 static and mas nmr as well as redor experiments give clear spectroscopic evidence of ga-o-ga connectivity. p-31/na-23 redor and reapdor results indicate that gallium has no dispersion effect on sodium ions in these glasses. they also indicate significant differences in the strength of dipolar interactions for distinct q(mga)(n) species, consistent with bond valence considerations. on the basis of these results, a comprehensive structural model is developed. this model explains the compositional trend of the glass transition temperatures in terms of the concentration of bridging oxygen species (p-o-p, p-o-ga, and ga-o-ga) in these glasses. the results provide new insights into the role of ga2o3 as an intermediate oxide, with features of both network modifier and network former in oxide glasses.
收录类别	SCI
语种	英语
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.siom.ac.cn/handle/181231/13142]
专题	上海光学精密机械研究所_中科院强激光材料重点实验室
作者单位	1.[Ren, Jinjun 2.Eckert, Hellmut] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany 3.[Ren, Jinjun] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China 4.[Eckert, Hellmut] Univ Sao Paulo, Inst Fi
推荐引用方式 GB/T 7714	Ren, Jinjun,Eckert, Hellmut. Intermediate Role of Gallium in Oxidic Glasses: Solid State NMR Structural Studies of the Ga2O3-NaPO3 System[J]. j. phys. chem. c,2014,118(28):15386.
APA	Ren, Jinjun,&Eckert, Hellmut.(2014).Intermediate Role of Gallium in Oxidic Glasses: Solid State NMR Structural Studies of the Ga2O3-NaPO3 System.j. phys. chem. c,118(28),15386.
MLA	Ren, Jinjun,et al."Intermediate Role of Gallium in Oxidic Glasses: Solid State NMR Structural Studies of the Ga2O3-NaPO3 System".j. phys. chem. c 118.28(2014):15386.