Hybrid Corannulene-Perylene Dyes: Facile Synthesis and Optoelectronic Properties

	Hybrid Corannulene-Perylene Dyes: Facile Synthesis and Optoelectronic Properties
	Lin, Zhi 1; Li, Cheng 1; Meng, Dong 1,2; Li, Yan 1; Wang, Zhaohui 1
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2016-10-01
卷号	11 期号:19 页码:2695-2699
关键词	corannulene cyclization imides organic optoelectronic devices perylene
英文摘要	Considering the peculiar topology of corannulene and extraordinary optoelectronic properties of perylene dyes, a series of hybrid corannulene-perylene dyes, namely corannulene-fused perylene-3,4-dicarboxylic acid monoimide (PMI) and corannulene-fused perylene-3,4,9,10-tetracarboxylic acid diimides (PDIs), were efficiently synthesized by a Suzuki coupling (carbon-carbon bond formation) and subsequent oxidative cyclization and photocyclization, respectively. Single crystal packing demonstrates that the solid state of the corannulene-fused PMI is arranged in back to back antiparallel dimers due to the strong dipole-dipole interactions. Integration of the corannulene unit to the perylene dyes along peri-positions makes the absorption bathochromically-shifted together with a much higher molar extinction coefficient, whereas integration of the corannulene unit to the perylene dyes along bay-positions has a much broader absorption. Strong and broad absorption properties, strong electron-accepting ability, and suitable LUMO levels close to that of [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) make hybrid corannulene-perylene dyes promising electron-acceptor materials for organic optoelectronic devices.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35105]
专题	化学研究所_有机固体实验室
作者单位	1.Chinese Acad Sci, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Lin, Zhi,Li, Cheng,Meng, Dong,et al. Hybrid Corannulene-Perylene Dyes: Facile Synthesis and Optoelectronic Properties[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(19):2695-2699.
APA	Lin, Zhi,Li, Cheng,Meng, Dong,Li, Yan,&Wang, Zhaohui.(2016).Hybrid Corannulene-Perylene Dyes: Facile Synthesis and Optoelectronic Properties.CHEMISTRY-AN ASIAN JOURNAL,11(19),2695-2699.
MLA	Lin, Zhi,et al."Hybrid Corannulene-Perylene Dyes: Facile Synthesis and Optoelectronic Properties".CHEMISTRY-AN ASIAN JOURNAL 11.19(2016):2695-2699.