Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2 | |
Zhang, Bingxing; Zhang, Jianling; Han, Buxing | |
刊名 | CHEMISTRY-AN ASIAN JOURNAL |
2016-10-01 | |
卷号 | 11期号:19页码:2610-2619 |
关键词 | carbon dioxide green chemistry ionic liquids metal-organic frameworks supercritical fluids |
英文摘要 | Ionic liquids (ILs) and supercritical carbon dioxide (scCO(2)) are both considered to be green solvents with tunable properties. Recently, studies of the synthesis of metal-organic frameworks (MOFs) in the presence of ILs and scCO(2) has become a burgeoning direction in chemistry and materials science. ILs have been shown to be ideal media for the synthesis of a variety of MOFs owing to their unique properties including the ability to dissolve a wide range of organic and inorganic compounds and flexible designability. scCO(2) has adjustable solvent power and excellent mass-transfer characteristics that offer the opportunity to replace organic solvents for MOF activation, MOF aerogel synthesis, and MOF construction. More interestingly, the simultaneous utilization of IL and scCO(2) can combine the advantages of the two liquids, which provides novel routes for the fabrication of MOF structures. This review describes the advances in MOF synthesis in ILs, scCO(2), and IL/scCO(2) systems. |
收录类别 | SCI |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/35096] |
专题 | 化学研究所_胶体、界面与化学热力学实验室 |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Bingxing,Zhang, Jianling,Han, Buxing. Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(19):2610-2619. |
APA | Zhang, Bingxing,Zhang, Jianling,&Han, Buxing.(2016).Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2.CHEMISTRY-AN ASIAN JOURNAL,11(19),2610-2619. |
MLA | Zhang, Bingxing,et al."Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2".CHEMISTRY-AN ASIAN JOURNAL 11.19(2016):2610-2619. |
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