Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2
Zhang, Bingxing; Zhang, Jianling; Han, Buxing
刊名CHEMISTRY-AN ASIAN JOURNAL
2016-10-01
卷号11期号:19页码:2610-2619
关键词carbon dioxide green chemistry ionic liquids metal-organic frameworks supercritical fluids
英文摘要Ionic liquids (ILs) and supercritical carbon dioxide (scCO(2)) are both considered to be green solvents with tunable properties. Recently, studies of the synthesis of metal-organic frameworks (MOFs) in the presence of ILs and scCO(2) has become a burgeoning direction in chemistry and materials science. ILs have been shown to be ideal media for the synthesis of a variety of MOFs owing to their unique properties including the ability to dissolve a wide range of organic and inorganic compounds and flexible designability. scCO(2) has adjustable solvent power and excellent mass-transfer characteristics that offer the opportunity to replace organic solvents for MOF activation, MOF aerogel synthesis, and MOF construction. More interestingly, the simultaneous utilization of IL and scCO(2) can combine the advantages of the two liquids, which provides novel routes for the fabrication of MOF structures. This review describes the advances in MOF synthesis in ILs, scCO(2), and IL/scCO(2) systems.
收录类别SCI
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/35096]  
专题化学研究所_胶体、界面与化学热力学实验室
作者单位Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Bingxing,Zhang, Jianling,Han, Buxing. Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(19):2610-2619.
APA Zhang, Bingxing,Zhang, Jianling,&Han, Buxing.(2016).Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2.CHEMISTRY-AN ASIAN JOURNAL,11(19),2610-2619.
MLA Zhang, Bingxing,et al."Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2".CHEMISTRY-AN ASIAN JOURNAL 11.19(2016):2610-2619.
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