Fabrication of Chiral-Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization

	Fabrication of Chiral-Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization
	Ma, Xiaojie 1,2; Zhang, Yibin 1,2; Zhang, Yifan 1,2; Liu, Yin 1,2; Che, Yanke 1,2; Zhao, Jincai 1,2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016-08-08
卷号	55 期号:33 页码:9538-9542
关键词	chirality nanotubes pathway complexity perylenediimide supramolecular polymerization
英文摘要	Novel, chiral-selective linear nanotubular heterojunctions were achieved by living supramolecular polymerization of perylenediimide (PDI) derivatives. We demonstrate that the chiral seed can effectively bias achiral PDI molecules to polymerize on its ends in the identical helical sense. More interestingly, the chiral seed can bias the opposite enantiomers to grow expitaxially from its ends even in excess amounts relative to the seed. Furthermore, we demonstrate that the biasing effect of the chiral seed on the opposite enantiomer is not dependent on the length of the chiral seed but is related to the intrinsic length of the elongated nanotube from the opposite enantiomer. The fabrication of chiral-selective nanotubes was achieved by application of the unique biasing effect of the chiral seed in living supramolecular self-assembly.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35301]
专题	化学研究所_光化学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Ma, Xiaojie,Zhang, Yibin,Zhang, Yifan,et al. Fabrication of Chiral-Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(33):9538-9542.
APA	Ma, Xiaojie,Zhang, Yibin,Zhang, Yifan,Liu, Yin,Che, Yanke,&Zhao, Jincai.(2016).Fabrication of Chiral-Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(33),9538-9542.
MLA	Ma, Xiaojie,et al."Fabrication of Chiral-Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.33(2016):9538-9542.