Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines

	Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines
	Zhang, Shu 1,2; Xing, Qifeng 1,2; Sun, Wen-Hua1,2,3
刊名	RSC ADVANCES
	2016
卷号	6 期号:76 页码:72170-72176
英文摘要	A series of 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines were reacted with cobalt chloride to form their corresponding cobalt complexes, which were further reacted with nickel chloride to form their binuclear heteronickel complexes. One of the representative cobalt-nickel complexes was unambiguously confirmed using single-crystal X-ray diffraction. Generally all mononuclear cobalt complexes and binuclear cobalt-nickel complexes showed good activities towards ethylene reactivity (oligomerization and polymerization), however, the mononuclear cobalt complexes showed much higher activities than the binuclear cobalt-nickel analogues, and this is described as the frustratingly synergic effect of heterometallic complexes in ethylene oligomerization. In addition, the obtained oligomers sometimes followed a Poisson distribution.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35316]
专题	化学研究所_工程塑料实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Shu,Xing, Qifeng,Sun, Wen-Hua. Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines[J]. RSC ADVANCES,2016,6(76):72170-72176.
APA	Zhang, Shu,Xing, Qifeng,&Sun, Wen-Hua.(2016).Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines.RSC ADVANCES,6(76),72170-72176.
MLA	Zhang, Shu,et al."Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines".RSC ADVANCES 6.76(2016):72170-72176.