Effect of calcination temperature on the catalytic activity of VPO for aldol condensation of acetic acid and formalin

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	Effect of calcination temperature on the catalytic activity of VPO for aldol condensation of acetic acid and formalin
	Yang, Dan 1,2; Sararuk, Chidchon 2; Suzuki, Kenzi 2; Li, Zengxi 1; Li, Chunshan 2
刊名	CHEMICAL ENGINEERING JOURNAL
	2016-09-15
卷号	300 期号:SEP 页码:160-168
关键词	VPO Aldol condensation Calcination temperature Acetic acid Formalin
ISSN号	1385-8947
英文摘要	The effect of calcination temperature on the catalytic activity of VPO catalyst for one step synthesis acrylic acid with acetic acid and formalin was systematically studied using a fixed-bed tubular micro reactor. The influence of calcination temperature on physicochemical properties especially crystal phase structure of VPO catalysts was obtained. The catalysts were analyzed and characterized with in situ high temperature XRD (HT-XRD), BET, TEM, TG/DTA, XPS, as well as NH3, CO2-TPD, and pyridine-FTIR methods. Larger special surface area and higher V4+ concentration favored higher conversion and selectivity. The optimum special surface area and I-V(4+)/I-V(5+) ratio was obtained with controlling calcination temperature. The catalyst deactivation was also explored. (C) 2016 Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Engineering, Environmental ; Engineering, Chemical
研究领域[WOS]	Engineering
关键词[WOS]	VANADIUM PYROPHOSPHATE OXIDES ; ACRYLIC-ACID ; METHYL-METHACRYLATE ; PROPIONIC-ACID ; PHOSPHATE CATALYSTS ; FORMALDEHYDE ; OXIDATION ; DEHYDRATION ; BASE ; GLYCEROL
收录类别	SCI
语种	英语
WOS记录号	WOS:000378181400016
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/21165]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.Univ Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yang, Dan,Sararuk, Chidchon,Suzuki, Kenzi,et al. Effect of calcination temperature on the catalytic activity of VPO for aldol condensation of acetic acid and formalin[J]. CHEMICAL ENGINEERING JOURNAL,2016,300(SEP):160-168.
APA	Yang, Dan,Sararuk, Chidchon,Suzuki, Kenzi,Li, Zengxi,&Li, Chunshan.(2016).Effect of calcination temperature on the catalytic activity of VPO for aldol condensation of acetic acid and formalin.CHEMICAL ENGINEERING JOURNAL,300(SEP),160-168.
MLA	Yang, Dan,et al."Effect of calcination temperature on the catalytic activity of VPO for aldol condensation of acetic acid and formalin".CHEMICAL ENGINEERING JOURNAL 300.SEP(2016):160-168.