Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst

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	Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst
	Song HY(宋河远)1,2 ; Jin RH(靳荣华)1 ; Jin FX(金福祥)1 ; Kang MR(康美荣)1; Li Z(李臻)1 ; Chen J(陈静)1 ; Chen J(陈静); Li Z(李臻)
刊名	Catalysts
	2016
卷号	6 期号:7 页码:106(1-8)
关键词	aldol condensation Knoevenagel condensation organocatalysis solvent-free condition ketone aldehyde
ISSN号	2073-4344
通讯作者	李臻 ; 陈静
英文摘要	Pyrrolidine and its derivatives were used to catalyze aldol and Knoevenagel condensations for the formation of the olefinic (C = C) bond under solvent-free conditions. The 3-pyrrolidinamine showed high activity and afforded excellent yields of alpha, beta-unsaturated compounds. The aldol condensation of aromatic/heterocyclic aldehydes with ketones affords enones in high conversion (99.5%) and selectivity (92.7%). Good to excellent yields of alpha, beta-unsaturated compounds were obtained in the Knoevenagel condensation of aldehydes with methylene-activated substrates.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (Project No. 21473225)
语种	英语
WOS记录号	WOS:000380771900015
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/20224]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Chen J(陈静); Li Z(李臻)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Song HY,Jin RH,Jin FX,et al. Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst[J]. Catalysts,2016,6(7):106(1-8).
APA	Song HY.,Jin RH.,Jin FX.,Kang MR.,Li Z.,...&李臻.(2016).Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst.Catalysts,6(7),106(1-8).
MLA	Song HY,et al."Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst".Catalysts 6.7(2016):106(1-8).