Chiral Bronsted Acid Catalyzed Enantioselective Phosphonylation of Allylamine via Oxidative Dehydrogenation Coupling
Cheng, Ming-Xing1; Ma, Ran-Song1; Yang, Qiang1; Yang SD(杨尚东)1,2
刊名Organic Letters
2016
卷号18期号:13页码:3262-3265
ISSN号1523-7060
通讯作者杨尚东
英文摘要

A new strategy for the synthesis of chiral α-amino phosphonates by enantioselective C–H phosphonylation of allylamine with phosphite in the presence of a chiral Brønsted acid catalyst has been developed. This protocol successfully integrates direct C–H oxidation with asymmetric phosphonylation and exhibits high enantioselectivity.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the NSFC (Nos. 21272100;21472076;21532001);Program for Changjiang Scholars and Innovative Research Team in University (IRT-15R28)
语种英语
WOS记录号WOS:000379455300056
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/20192]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Ming-Xing,Ma, Ran-Song,Yang, Qiang,et al. Chiral Bronsted Acid Catalyzed Enantioselective Phosphonylation of Allylamine via Oxidative Dehydrogenation Coupling[J]. Organic Letters,2016,18(13):3262-3265.
APA Cheng, Ming-Xing,Ma, Ran-Song,Yang, Qiang,&Yang SD.(2016).Chiral Bronsted Acid Catalyzed Enantioselective Phosphonylation of Allylamine via Oxidative Dehydrogenation Coupling.Organic Letters,18(13),3262-3265.
MLA Cheng, Ming-Xing,et al."Chiral Bronsted Acid Catalyzed Enantioselective Phosphonylation of Allylamine via Oxidative Dehydrogenation Coupling".Organic Letters 18.13(2016):3262-3265.
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