CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3 | |
Shang JP(尚建鹏)1; Guo, Xiaoguang2; Li, Zuopeng1; Deng YQ(邓友全)3 | |
刊名 | Green Chemistry |
2016 | |
卷号 | 18期号:10页码:3082-3088 |
ISSN号 | 1463-9262 |
通讯作者 | 尚建鹏 |
英文摘要 | This paper reports an effective route for the syntheses of hydroxy carbamates from the reaction of CO2, epoxides and amines catalyzed by a Au/Fe2O3 catalyst. Under the optimized reaction conditions, various hydroxy carbamates were successfully synthesized with 92–98% isolated yields. The catalyst could be reused for several runs without deactivation. A plausible reaction mechanism was proposed by which the hydroxy carbamate was formed through an ammonium carbamate intermediate and the catalyst mainly promoted further nucleophilic addition between the epoxide and ammonium carbamate. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the Doctoral Scientific Research Foundation of Shanxi Datong University (2012-B-12);Basic Research Programs of Science and Technology Department of Datong (2015107);National Natural Science Foundation of China (no: 21473185;U1532117) |
语种 | 英语 |
WOS记录号 | WOS:000376082400022 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/20101] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Shanxi Datong Univ, Dept Chem & Environm Engn, Datong 037009, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Shang JP,Guo, Xiaoguang,Li, Zuopeng,et al. CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3[J]. Green Chemistry,2016,18(10):3082-3088. |
APA | Shang JP,Guo, Xiaoguang,Li, Zuopeng,&Deng YQ.(2016).CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3.Green Chemistry,18(10),3082-3088. |
MLA | Shang JP,et al."CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3".Green Chemistry 18.10(2016):3082-3088. |
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