| Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions | |
Lv, Hui1,2; Xing Q(邢琦)2 ; Yue CT(岳成涛)2; Lei, Ziqiang1; Li FW(李福伟)2; Li FW(李福伟); Li FW(李福伟)
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| 刊名 | Chemical Communications
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| 2016 | |
| 卷号 | 52期号:39页码:6545-6548 |
| ISSN号 | 1359-7345 |
| 通讯作者 | Lei, Ziqiang ; 李福伟 |
| 英文摘要 | An unprecedented catalyst-free formylation of amines using CO2 and hydrosilanes was developed. The solvent plays a vital role in promoting the interaction of amines with hydrosilanes and subsequent CO2 insertion, thus facilitating the simultaneous activation of N–H and Si–H bonds. Based on relevant mechanistic studies, a plausible mechanism involving a silyl carbamate intermediate is proposed. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21373246;21522309) |
| 语种 | 英语 |
| WOS记录号 | WOS:000375625000010 |
| 内容类型 | 期刊论文 |
| 源URL | [http://210.77.64.217/handle/362003/20083]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_苏州研究院 |
| 通讯作者 | Li FW(李福伟); Li FW(李福伟) |
| 作者单位 | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Hui,Xing Q,Yue CT,et al. Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions[J]. Chemical Communications,2016,52(39):6545-6548. |
| APA | Lv, Hui.,Xing Q.,Yue CT.,Lei, Ziqiang.,Li FW.,...&李福伟.(2016).Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions.Chemical Communications,52(39),6545-6548. |
| MLA | Lv, Hui,et al."Solvent-promoted catalyst-free N-formylation of amines using carbon dioxide under ambient conditions".Chemical Communications 52.39(2016):6545-6548. |
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