Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics
Song HY(宋河远)1,2; Jin FX(金福祥)1; Jin RH(靳荣华)1; Kang MR(康美荣)1; Li Z(李臻)1; Chen J(陈静)1; Li Z(李臻); Chen J(陈静)
刊名Catalysis Letters
2016
卷号146期号:7页码:1264-1272
关键词Formaldehyde Methylation Diarylmethane Ionic liquids
ISSN号1011-372X
通讯作者李臻 ; 陈静
英文摘要

Methylation of formaldehyde with various aromatics under functional ionic liquids catalysis has been developed. Among the ionic liquids investigated, triphenyl-(4-sulfobutyl)-phosphonium triflate ([TTPBs][CF3SO3]) showed high activity and afforded excellent yields of diarylmethane derivatives. A mechanism for the catalytic performance of [TTPBs][CF3SO3] is proposed. Besides, the catalyst can simply be separated from the reaction mixture by centrifugation and be recycled ten times without noticeable loss of activity.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (Project No. 21473225;21133011)
语种英语
WOS记录号WOS:000378816600012
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/19806]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Li Z(李臻); Chen J(陈静)
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Song HY,Jin FX,Jin RH,et al. Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics[J]. Catalysis Letters,2016,146(7):1264-1272.
APA Song HY.,Jin FX.,Jin RH.,Kang MR.,Li Z.,...&陈静.(2016).Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics.Catalysis Letters,146(7),1264-1272.
MLA Song HY,et al."Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics".Catalysis Letters 146.7(2016):1264-1272.
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