Phase equilibria of CO2 hydrate in NaCl-MgCl2 aqueous solutions | |
Zha, Li1,2; Liang, De-Qing1; Li, Dong-Liang1 | |
刊名 | journal of chemical thermodynamics |
2012-12-01 | |
卷号 | 55页码:110-114 |
关键词 | CO2 hydrate Phase equilibrium MgCl2 NaCl |
英文摘要 | phase equilibrium data for co2 hydrate in presence of binary nacl-mgcl2 aqueous solutions were obtained at four different concentrations (2 wt%nacl-8 wt%mgcl2, 8 wt%nacl-2wt%mgcl2, 5 wt% nacl-15 wt%mgcl2, 15 wt% nacl-5 wt%mgcl2) in the temperature range of (258.63 to 276.45) k and in the pressure range of (1.34 to 3.41) mpa, respectively. the measurements were carried out by employing isochoric pressure search method with uncertainties of +/- 0.1 k for temperature and +/- 0.02 mpa for pressure. the hydrate equilibrium data for the (co2 + water) system were compared with some experimental data from the literature, and the acceptable agreement demonstrated the reliability of the experimental method used in this work. the van der waals and platteeuw (vdw-p) solid solution theory was used to model the hydrate phase, and the equation of weiss combined with pitzer-based model was applied to characterize the activity of water. the predicted results were in good consistency with the experimental data, and the average pressure deviation was 5.13%. (c) 2012 elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | thermodynamics ; chemistry, physical |
研究领域[WOS] | thermodynamics ; chemistry |
关键词[WOS] | carbon-dioxide ; electrolyte solutions ; dissociation pressures ; clathrate-hydrate ; gas-mixtures ; methane ; mgcl2 ; prediction ; alcohol ; systems |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000308075000016 |
内容类型 | 期刊论文 |
源URL | [http://ir.giec.ac.cn/handle/344007/10159] |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zha, Li,Liang, De-Qing,Li, Dong-Liang. Phase equilibria of CO2 hydrate in NaCl-MgCl2 aqueous solutions[J]. journal of chemical thermodynamics,2012,55:110-114. |
APA | Zha, Li,Liang, De-Qing,&Li, Dong-Liang.(2012).Phase equilibria of CO2 hydrate in NaCl-MgCl2 aqueous solutions.journal of chemical thermodynamics,55,110-114. |
MLA | Zha, Li,et al."Phase equilibria of CO2 hydrate in NaCl-MgCl2 aqueous solutions".journal of chemical thermodynamics 55(2012):110-114. |
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