Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source

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	Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source
	Chen, Aibing 1; Li, Yonglei 1,2; Chen, Jinzhu 2; Zhao, Guoying 1,2; Ma, Longlong 2; Yu, Yifeng 1
刊名	chempluschem
	2013-11-01
卷号	78 期号:11 页码:1370-1378
关键词	hydrogenation nanostructures palladium polymers sodium formate
英文摘要	selective hydrogenation of phenol to cyclohexanone over a catalyst of polyaniline-functionalized carbon-nanofiber-supported palladium (pd-pani/cnf) with sodium formate as the hydrogen source has been studied. phenol conversion exceeding 99% was achieved with a cyclohexanone selectivity of >99% in aqueous media. in an extension to pd-pani/cnf, polymers such as polypyrrole (ppy), poly(4-vinylpyridine) (pvp), and poly(1-vinylimidazole) (pvi) were further applied to a catalyst of pd-polymer/cnf for selective phenol hydrogenation. all of the pd-polymer/cnf catalysts showed excellent to good performance toward selective phenol hydrogenation. however, pd-pani/cnf was considerably more active and selective to afford the desired cyclohexanone than pd-ppy/cnf, pd-pvp/cnf, and pd-pvi/cnf. moreover, a series of phenol-derived compounds were selectively hydrogenated in high yields under the investigated aqueous conditions. the research highlights an environmentally benign and effective process for the selective reduction of phenol derivatives with sodium formate as an alternative hydrogen source.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	asymmetric transfer hydrogenation ; aqueous-media ; catalysts ; nanotubes ; water ; polyaniline ; oxidation ; nanoparticles ; dioxide ; dehydrogenation
收录类别	SCI ; CCR
语种	英语
WOS记录号	WOS:000326900600013
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/10120]
专题	中国科学院广州能源研究所
作者单位	1.Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CSA Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Chen, Aibing,Li, Yonglei,Chen, Jinzhu,et al. Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source[J]. chempluschem,2013,78(11):1370-1378.
APA	Chen, Aibing,Li, Yonglei,Chen, Jinzhu,Zhao, Guoying,Ma, Longlong,&Yu, Yifeng.(2013).Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source.chempluschem,78(11),1370-1378.
MLA	Chen, Aibing,et al."Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source".chempluschem 78.11(2013):1370-1378.