Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis | |
Lin JH(林锦鸿); Xiao JC(肖吉昌) | |
刊名 | Tetrahedron Lett. |
2014 | |
卷号 | 55期号:45页码:6147-6155 |
其他题名 | 不对称有机催化氟化与氟烷基化反应研究进展 |
通讯作者 | 肖吉昌 |
英文摘要 | The past decade has witnessed the significant advances of asymmetric organocatalytic fluorination, monofluoroalkylation, gem-difluoroalkylation, and trifluoromethylation. This digest summarizes the latest progress of these reactions. In the research area of asymmetric organocatalytic fluorination, a new catalysis concept, chiral anion phase-transfer catalysis strategy, has emerged and has proved to be highly efficient. Asymmetric organocatalytic monofluoroalkylation and gem-difluoroalkylation have been much less explored and the Lewis base/acid catalysis has been the most used strategy. Compared with electrophilic trifluoromethylation, nucleophilic trifluoromethylation has been intensively studied in the research field of asymmetric organocatalytic trifluoromethylation. (C) 2014 Published by Elsevier Ltd. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tetlet.2014.09.031 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/38870] |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Lin JH,Xiao JC. Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis[J]. Tetrahedron Lett.,2014,55(45):6147-6155. |
APA | 林锦鸿,&肖吉昌.(2014).Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis.Tetrahedron Lett.,55(45),6147-6155. |
MLA | 林锦鸿,et al."Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis".Tetrahedron Lett. 55.45(2014):6147-6155. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论