Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides | |
Zhu SQ(朱圣卿)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1 | |
刊名 | Eur. J. Org. Chem.
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2014 | |
期号 | 21页码:4453-4456 |
其他题名 | 末端炔烃与AgSCF3的氧化三氟甲硫基化: 一个方便途径制备炔三氟甲硫基化合物 |
通讯作者 | 卿凤翎 |
英文摘要 | A new method for the efficient synthesis of alkynyl trifluoromethyl sulfides was developed. By combining AgSCF3 and NCS in N,N-dimethylacetamide, an electrophilic active intermediate was produced, which was then treated with a variety of terminal alkynes to afford the corresponding trifluoromethanesulfenylated products in moderate to excellent yields. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/ejoc.201402533 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/38848] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
作者单位 | 1.中科院上海有机化学研究所 2.东华大学 |
推荐引用方式 GB/T 7714 | Zhu SQ,Xu XH,Qing FL. Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides[J]. Eur. J. Org. Chem.,2014(21):4453-4456. |
APA | 朱圣卿,徐修华,&卿凤翎.(2014).Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides.Eur. J. Org. Chem.(21),4453-4456. |
MLA | 朱圣卿,et al."Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides".Eur. J. Org. Chem. .21(2014):4453-4456. |
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