Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds

	Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds
	Ceng YW(曾裕文); Hu JB(胡金波)
刊名	Chem.-Eur. J.
	2014
卷号	20 期号:23 页码:6866-6870
其他题名	银催化下芳炔对全氟烷基碘的表观插入反应
通讯作者	胡金波
英文摘要	An unprecedented silver-catalyzed formal insertion of arynes into RfI (Rf=CF3, C2F5) bonds has been developed. This protocol provides easy access to various ortho-perfluoroalkyl iodoarenes under mild conditions. In this insertion reaction, an ionic atom-transfer reaction of RfI occurs, and a silver-mediated metathesis process is involved in the efficient transfer of the electropositive iodine atom.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/chem.201402846
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38822]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Ceng YW,Hu JB. Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds[J]. Chem.-Eur. J.,2014,20(23):6866-6870.
APA	曾裕文,&胡金波.(2014).Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds.Chem.-Eur. J.,20(23),6866-6870.
MLA	曾裕文,et al."Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds".Chem.-Eur. J. 20.23(2014):6866-6870.