Synthesis of alpha-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysis

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	Synthesis of alpha-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysis
	Li L(李伦); Chen QY(陈庆云); Guo Y(郭勇)
刊名	J. Fluor. Chem.
	2014
卷号	167 页码:79-83
其他题名	可见光促进的亲电三氟甲基化试剂与烯烃的反应
通讯作者	陈庆云 ; 郭勇
英文摘要	alpha-Trifluoromethyl ketones are important fluorinated intermediates and products in chemical synthesis and medicinal development. Herein, visible light-catalyzed photoredox trifluoromethylation of 1-aryl-2-alkyl substituted alkenes using an electrophilic trifluoromethylating reagent to produce alpha-trifluoromethyl ketones is reported. Two possible pathways involving either a trifluoromethyl radical or a styrene radical cation are proposed and discussed. (C) 2014 Elsevier B.V. All rights reserved.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.jfluchem.2014.05.013
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38811]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Li L,Chen QY,Guo Y. Synthesis of alpha-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysis[J]. J. Fluor. Chem.,2014,167:79-83.
APA	李伦,陈庆云,&郭勇.(2014).Synthesis of alpha-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysis.J. Fluor. Chem.,167,79-83.
MLA	李伦,et al."Synthesis of alpha-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysis".J. Fluor. Chem. 167(2014):79-83.