Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex

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	Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex
	Cui Z(崔哲)1; Chen YJ(陈亚静)1; Gao WY(高文运)1; Feng CG(冯陈国)1; Lin GQ(林国强)1
刊名	Org. Lett.
	2014
卷号	16 期号:3 页码:1016-1019
其他题名	Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex
通讯作者	高文运 ; 冯陈国 ; 林国强
英文摘要	An efficient rhodium-catalyzed asymmetric addition reaction of potassium alkenyltrifluoroborates to N-nosylaldimines has been developed. Under optimal conditions, the reactions proceeded with good to excellent yields and excellent enantioselectivities (97 -> 99% ee). The utility of this method is demonstrated by the formal synthesis of (-)-aurantioclavine.
学科主题	天然产物有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol5000154
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38971]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
作者单位	1.西北大学 2.中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Cui Z,Chen YJ,Gao WY,et al. Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex[J]. Org. Lett.,2014,16(3):1016-1019.
APA	崔哲,陈亚静,高文运,冯陈国,&林国强.(2014).Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex.Org. Lett.,16(3),1016-1019.
MLA	崔哲,et al."Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium-Diene Complex".Org. Lett. 16.3(2014):1016-1019.