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	Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
	Tian B(田兵)1; Liu Q(刘强)1; TONG XIAOFENG1; Tian P(田平)1; Lin GQ(林国强)1
刊名	Org. Chem. Front.
	2014
卷号	1页码:1116-112
其他题名	Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates
通讯作者	田平 ; 林国强
英文摘要	Copper(I)-catalyzed enantioselective hydroboration of 3-aryl substituted cyclopropene-3-carboxylate is described, providing chiral cyclopropylboronates with excellent enantioselectivities (89–95% ee) in moderate to high yields (55–86%). The non-directing effect of the ester group was observed, and the reaction proceeded with solely trans-selectivity. The chiral boronates could be conveniently converted into chiral 1,2-diaryl substituted cyclopropane derivatives.
学科主题	天然产物有机化学
原文出处	http://dx.doi.org/10.1039/c4qo00157e
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38970]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
作者单位	1.中科院上海有机化学研究所 2.华东理工大学
推荐引用方式 GB/T 7714	Tian B,Liu Q,TONG XIAOFENG,et al. Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates[J]. Org. Chem. Front.,2014,1:1116-112.
APA	田兵,刘强,TONG XIAOFENG,田平,&林国强.(2014).Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates.Org. Chem. Front.,1,1116-112.
MLA	田兵,et al."Copper(I)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates".Org. Chem. Front. 1(2014):1116-112.

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