Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution

	Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution
	Chen, X; Deng, XB; Ma, H; Tao, JZ; Zhao, XH; Tao JZ(陶举洲)
刊名	JOURNAL OF SOLID STATE CHEMISTRY
	2011
卷号	184 期号:5 页码:1090-1095
关键词	Synthesis Solid solution Negative thermal expansion
通讯作者	[Chen, Xi ; Deng, Xuebin ; Ma, Hui ; Zhao, Xinhua] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China ; [Chen, Xi ; Deng, Xuebin ; Ma, Hui ; Zhao, Xinhua] Beijing Normal Univ, Anal & Test Ctr, Beijing 100875, Peoples R China ; [Tao, Juzhou] Chinese Acad Sci, Inst High Energy Phys, Expt Phys Ctr, Beijing 100049, Peoples R China ; [Chen, Xi] N China Univ Water Source & Elect Power, Sch Civil Engn & Commun, Zhengzhou 450011, Peoples R China
英文摘要	Tetragonal ZrW1.80V0.20O6.90(OH)(2.00)(H2O)(2.00) hydrate was prepared using an acidic steam hydrothermal (ASH) method. Thermal dehydration followed by phase transformation of this precursor leads to successful synthesis of a novel W-site low-valent substituted cubic ZrW1.80V0.20O7.90 solid solution, the mechanism of this process is studied in detail revealing the hydrate and a metastable orthorhombic phase of V'(W)substitution solid solution as important intermediate product. This material is found to possess thermal contraction and order-disorder phase transformation properties similar to that of the cubic ZrW2O8. (C) 2011 Elsevier Inc. All rights reserved.
学科主题	Chemistry
类目[WOS]	Chemistry, Inorganic & Nuclear ; Chemistry, Physical
研究领域[WOS]	Chemistry
原文出处	SCI
语种	英语
WOS记录号	WOS:000290549900018
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/239032]
专题	高能物理研究所_实验物理中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Chen, X,Deng, XB,Ma, H,et al. Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution[J]. JOURNAL OF SOLID STATE CHEMISTRY,2011,184(5):1090-1095.
APA	Chen, X,Deng, XB,Ma, H,Tao, JZ,Zhao, XH,&陶举洲.(2011).Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution.JOURNAL OF SOLID STATE CHEMISTRY,184(5),1090-1095.
MLA	Chen, X,et al."Hydrothermal synthesis and thermal properties of a novel cubic ZrW1.80V0.20O7.90 solid solution".JOURNAL OF SOLID STATE CHEMISTRY 184.5(2011):1090-1095.