Utilizing 3d-4f Magnetic Interaction to Slow the Magnetic Relaxation of Heterometallic Complexes

	Utilizing 3d-4f Magnetic Interaction to Slow the Magnetic Relaxation of Heterometallic Complexes
	Li,Xiao-Lei; Min,Fan-Yong; Wang,Chao; Lin,Shuang-Yan; Liu,Zhiliang; Tang,Jinkui
刊名	inorganic chemistry
	2015
卷号	54 期号:9 页码:4337-4344
关键词	SINGLE-MOLECULE MAGNET HIGH-SPIN MOLECULES DY-III GD-III TB-III ANISOTROPY BARRIER SMM BEHAVIOR HO-III CO-II LN
通讯作者	liu,zl
英文摘要	the synthesis, structural characterization, and magnetic properties of four related heterometallic complexes with formulas [(dy2coii)-co-iii(c7h5o2)(8)] 6h(2)o (1), [(dy2niii)-ni-iii(c7h5o2)(8)] (c7h6o2)(2) (2), (tb2coii)-co-iii(c7h5o2)(8) (3), and (dy2cdii)-cd-iii(c7h5o2)(8) (4) were reported. each of complexes has a perfectly linear arrangement of the metal ions with two terminal ln(iii) (ln(iii) = dy-iii, tb-iii) ions and one central m-ii (m-ii = co-ii, ni-ii, cd-ii) ion. it was found that 13 displayed obvious magnetic interactions between the spin carriers according to the direct current (dc) susceptibility measurements. alternating current (ac) magnetic susceptibility measurements indicate that complexes 1-4 all exhibit single-molecule magnet (smm) behavior, while the replacement of the diamagnetic cdii by paramagnetic ions leads to a significant slowing of the relaxation thanks to the magnetic interactions between 3d and 4f ions, resulting in higher relaxation barrier for complexes 1 and 2. moreover, both dy2co and dy2ni compounds exhibit dual relaxation pathways that may originate from the single ion behavior of individual dy-iii ions and the coupling between dy-iii and co-ii/ni-ii ions, respectively, which can be taken as the feature of 3d-4f smms. the u-eff for 1 of 127 k is a relatively high value among the reported 3d-4f smms. the results demonstrate that the magnetic coupling between 3d and 4f ions is crucial to optimize smm parameters. the synthetic approach illustrated in this work represents an efficient route to design nd-4f based smms via incorporating suitable paramagnetic 3d and even 4d and 5d ions into the df system.
收录类别	SCI
语种	英语
WOS记录号	WOS:000354075600022
公开日期	2016-05-31
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/65070]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Li,Xiao-Lei,Min,Fan-Yong,Wang,Chao,et al. Utilizing 3d-4f Magnetic Interaction to Slow the Magnetic Relaxation of Heterometallic Complexes[J]. inorganic chemistry,2015,54(9):4337-4344.
APA	Li,Xiao-Lei,Min,Fan-Yong,Wang,Chao,Lin,Shuang-Yan,Liu,Zhiliang,&Tang,Jinkui.(2015).Utilizing 3d-4f Magnetic Interaction to Slow the Magnetic Relaxation of Heterometallic Complexes.inorganic chemistry,54(9),4337-4344.
MLA	Li,Xiao-Lei,et al."Utilizing 3d-4f Magnetic Interaction to Slow the Magnetic Relaxation of Heterometallic Complexes".inorganic chemistry 54.9(2015):4337-4344.