Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones | |
Li JW(李加文)1,2; Qin GP(秦贵平)1,2; Liu Y(刘洋)1,2; Huang HM(黄汉民)1 | |
刊名 | Organic chemistry frontiers |
2016 | |
卷号 | 3期号:2页码:259-267 |
ISSN号 | 2052-4129 |
通讯作者 | 黄汉民 |
英文摘要 | Palladium-catalysed cross-coupling of aminals with N-sulfonyl hydrazones has been established via C–N bond activation under base-free conditions, in which one C–C bond and one C–S bond were simultaneously generated. It was successfully applied in the construction of a variety of aminomethyl substituted allylic sulfones. Preliminary mechanistic studies indicated that the unique electrophilic cyclopalladated complex was involved in the catalytic cycle. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (21222203;21372231;21133011);Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000369535800017 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/19719] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li JW,Qin GP,Liu Y,et al. Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones[J]. Organic chemistry frontiers,2016,3(2):259-267. |
APA | Li JW,Qin GP,Liu Y,&Huang HM.(2016).Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones.Organic chemistry frontiers,3(2),259-267. |
MLA | Li JW,et al."Palladium-catalysed coupling reaction of aminals with N-sulfonyl hydrazones to give allylic sulfones".Organic chemistry frontiers 3.2(2016):259-267. |
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