Synthesis of conjugated microporous polymers for gas storage and selective adsorption

	Synthesis of conjugated microporous polymers for gas storage and selective adsorption
	Shi, Qian 1; Sun, Hanxue 1; Yang, Ruixia 2; Zhu, Zhaoqi 1; Liang, Weidong 1; Tan, Dazhi 3; Yang, Baoping 1; Li, An 1; Deng, Weiqiao 2
刊名	journal of materials science
	2015-10-01
卷号	50 期号:19 页码:6388-6394
英文摘要	two novel cmps networks with (a(4) + b-3) type and (a(4) + b-2) type were synthesized by pb(ii)/cu(i)-catalyzed sonogashira-hagihara cross-coupling polymerization. the resulting cmps show high thermal stability with a decomposition temperature above 300 degrees c. the cmps exhibit high specific surface areas up to 788 m(2) g(-1). using them as porous platforms, the co2 adsorption of cmps was investigated. meanwhile, the synthesized cmps show surface superhydrophobicity with water contact angle about 157 degrees due to the microporous morphological structures and the strongly hydrophobic chemical compositions. the organic liquid uptake of cmps samples was measured up to 1522 wt% for a variety of organic solvents. furthermore, simply coating of the resulting cmps on the stainless steel grid enables the wettability of grid changing from hydrophilicity to superhydrophobicity and superoleophilicity, which makes them potential candidates for selective adsorption of oils and organics from water.
WOS标题词	science & technology ; technology
类目[WOS]	materials science, multidisciplinary
研究领域[WOS]	materials science
关键词[WOS]	covalent organic frameworks ; triazine-based frameworks ; hydrogen storage ; surface-area ; visible-light ; mesh film ; networks ; transportation ; morphologies ; absorption
收录类别	SCI
语种	英语
WOS记录号	WOS:000358149600015
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146403]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China 2.Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
推荐引用方式 GB/T 7714	Shi, Qian,Sun, Hanxue,Yang, Ruixia,et al. Synthesis of conjugated microporous polymers for gas storage and selective adsorption[J]. journal of materials science,2015,50(19):6388-6394.
APA	Shi, Qian.,Sun, Hanxue.,Yang, Ruixia.,Zhu, Zhaoqi.,Liang, Weidong.,...&Deng, Weiqiao.(2015).Synthesis of conjugated microporous polymers for gas storage and selective adsorption.journal of materials science,50(19),6388-6394.
MLA	Shi, Qian,et al."Synthesis of conjugated microporous polymers for gas storage and selective adsorption".journal of materials science 50.19(2015):6388-6394.