Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds

	Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds
	Jiang, Quanbin 1; Guo, Tenglong 1; Yu, Zhengkun 1,2
刊名	chemcatchem
	2015-02-01
卷号	7 期号:4 页码:660-665
关键词	asymmetric catalysis copper enones homogeneous catalysis ketones
英文摘要	the cu-catalyzed, one-pot tandem (asymmetric) borylation of -chloroalkyl aryl ketones via the insitu generated acyclic enones with bis(pinacolato)diboron was achieved efficiently to reach up to 97% yield and 99% enantioselectivity for the formal sp(3) ccl borylation products. the present methodology provides an efficient alternative route to (chiral) alkylboron compounds.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	alpha,beta-unsaturated carbonyl-compounds ; boron conjugate additions ; enantioselective synthesis ; saturated ketones ; bond formation ; boration ; esters ; alcohols ; oxidation ; enones
收录类别	SCI
语种	英语
WOS记录号	WOS:000349917900017
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145962]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Quanbin,Guo, Tenglong,Yu, Zhengkun. Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds[J]. chemcatchem,2015,7(4):660-665.
APA	Jiang, Quanbin,Guo, Tenglong,&Yu, Zhengkun.(2015).Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds.chemcatchem,7(4),660-665.
MLA	Jiang, Quanbin,et al."Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds".chemcatchem 7.4(2015):660-665.