Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions

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	Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions
	Zhou, Huacong 1,2; Song, Jinliang 1; Meng, Qinglei 1; He, Zhenhong 1; Jiang, Zhiwei 1; Zhou, Baowen 1; Liu, Huizhen 1; Han, Buxing 1
刊名	GREEN CHEMISTRY
	2016
卷号	18 期号:1 页码:220-225
英文摘要	Conversion of biomass into 2,5-dimethyltetrahydrofuran (DMTHF), an excellent fuel additive, solvent, and industrial intermediate, is an important reaction in green chemistry. In this work, different combinations of supported metal catalysts and solid acids were investigated for the synthesis of DMTHF from biomass derived diketone (2,5-hexanedione, 2,5-HD). The results showed that commercial Pt/C and solid acid Amberlite (R) IR-120H had an excellent cooperative effect on the reaction. 2,5-HD could be converted into DMTHF with a yield up to 99% under milder conditions. Further experiments indicated that 2,5-hexanediol (2,5-HDO) is a key intermediate in the reaction. The catalyst system could be facilely recovered due to the heterogeneity and reused several times without notable change in the performance.
收录类别	SCI
语种	英语
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/29527]
专题	化学研究所_胶体、界面与化学热力学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Inner Mongolia Univ Technol, Chem Engn Coll, Hohhot 010051, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Huacong,Song, Jinliang,Meng, Qinglei,et al. Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions[J]. GREEN CHEMISTRY,2016,18(1):220-225.
APA	Zhou, Huacong.,Song, Jinliang.,Meng, Qinglei.,He, Zhenhong.,Jiang, Zhiwei.,...&Han, Buxing.(2016).Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions.GREEN CHEMISTRY,18(1),220-225.
MLA	Zhou, Huacong,et al."Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions".GREEN CHEMISTRY 18.1(2016):220-225.