Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis

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	Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis
	Wang, Yuelun 1; Jiang, Yuan 1; Huang, Jun 1; Liang, Jing 1; Wang, Hui 2; Li, Zhuo 2; Wu, Jinhu 2; Li, Min 1; Zhao, Yunpeng 1; Niu, Jiachen 1
刊名	FUEL
	2016-06-15
卷号	174 页码:17-24
关键词	Fischer-Tropsch synthesis Hierarchical zeolites Crystalline Cobalt catalyst
英文摘要	Mesoporous ZSM-5 was synthesized using double-template method and its application in FischerTropsch synthesis (FTS) was studied. By comparison, ZSM-5 and SBA-15 were also prepared. The results demonstrated that the catalysts with bimodal structure and moderate acidity showed higher C5-18 selectivity with relatively lower CH4 selectivity, while higher C5-12 selectivity over Co/ZSM-5 catalyst and higher C12-18 selectivity over Co/SBA-15 catalyst were observed, respectively. Cobalt loaded on crystalline mesoporous ZSM-5 showed the lowest deactivated rate, which suggested that such bimodal structure was favor to the stabilization of cobalt particles. As a result of lower hydrothermal stability of mesopority, Co/SBA-15 catalyst had the fastest deactivation. (c) 2016 Elsevier Ltd. All rights reserved.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Energy & Fuels ; Engineering, Chemical
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	SUPPORTED RUTHENIUM NANOPARTICLES ; C-5-C-11 ISOPARAFFINS ; CO HYDROGENATION ; PORE-SIZE ; ZEOLITE ; DEACTIVATION ; PERFORMANCE ; MESOPOROSITY ; SELECTIVITY ; DISPERSION
收录类别	SCI
语种	英语
WOS记录号	WOS:000370530600003
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/8014]
专题	青岛生物能源与过程研究所_热化学转化事业部
作者单位	1.China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China 2.Chinese Acad Sci, Key Lab Biofuel, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yuelun,Jiang, Yuan,Huang, Jun,et al. Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis[J]. FUEL,2016,174:17-24.
APA	Wang, Yuelun.,Jiang, Yuan.,Huang, Jun.,Liang, Jing.,Wang, Hui.,...&Niu, Jiachen.(2016).Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis.FUEL,174,17-24.
MLA	Wang, Yuelun,et al."Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis".FUEL 174(2016):17-24.