Rational control on floating catalysts for the growth of carbon nanotube assemblies: From vertically aligned carbon nanotube arrays to carbon nanotube films
Chen, HY(陈宏源); Chen, MH(陈名海); Zhang, YY(张永毅); Li, QW(李清文)
刊名APPLIED SURFACE SCIENCE
2015
卷号353页码:11
关键词Carbon nanotube Floating catalyst Vertically aligned array Film Growth control
通讯作者Chen, MH (陈名海)
英文摘要Floating catalyst chemical vapor deposition (FCCVD) has been widely used for the growth of various carbon nanotube (CNT) macrostructures, mainly including vertically aligned CNT (VACNT) arrays and none-woven CNT films. However, it is still unclear for the reason why these CNT macrostructures with largely different morphologies were received via the similar method. In this research, it revealed that the growth temperature largely affected the nucleation status of floating catalysts and thus controlled the morphologies of CNT macrostructures from VACNT arrays to none-woven CNT films. In low temperatures (below 800 degrees C), VACNTs were grown by bottom-up mechanism with several CNTs, but not one individual from bottom to up along the array height direction. Furthermore, VACNT arrays were only grown on some substrates that can induce iron atoms aggregating to catalyst particles with a suitable size. When increasing the growth temperature higher than 800 degrees C, more catalyst particles were nucleated in the gas flow, which induced the formation of none-woven CNT films composed of thin CNTs (single-walled CNTs and double-walled CNTs). This research was significative for understanding CNT growth mechanism via FCCVD process and the synthesis of different CNT macrostructures by this strategy. (C) 2015 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
公开日期2016-05-03
内容类型期刊论文
源URL[http://ir.sinano.ac.cn/handle/332007/3287]  
专题苏州纳米技术与纳米仿生研究所_先进材料研究部_李清文团队
推荐引用方式
GB/T 7714
Chen, HY,Chen, MH,Zhang, YY,et al. Rational control on floating catalysts for the growth of carbon nanotube assemblies: From vertically aligned carbon nanotube arrays to carbon nanotube films[J]. APPLIED SURFACE SCIENCE,2015,353:11.
APA Chen, HY,Chen, MH,Zhang, YY,&Li, QW.(2015).Rational control on floating catalysts for the growth of carbon nanotube assemblies: From vertically aligned carbon nanotube arrays to carbon nanotube films.APPLIED SURFACE SCIENCE,353,11.
MLA Chen, HY,et al."Rational control on floating catalysts for the growth of carbon nanotube assemblies: From vertically aligned carbon nanotube arrays to carbon nanotube films".APPLIED SURFACE SCIENCE 353(2015):11.
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