Vertically Aligned Carbon Nanotubes on Carbon Nanofibers: A Hierarchical Three-Dimensional Carbon Nanostructure for High-Energy Flexible Supercapacitors
Qiu, YC(丘勇才); Li, GZ(李桂珠); Hou, Y(侯远); Pan, ZH; Li, HF(李洪飞); Li, WF(李宛飞); Liu, MN(刘美男); Ye, FM(叶方敏); Yang, XW(杨晓伟); Zhang, YG(张跃刚)
刊名CHEMISTRY OF MATERIALS
2015
卷号27期号:4页码:7
通讯作者Yang, XW (杨晓伟)
英文摘要Hierarchical structures enable high-performance power sources. We report here the preparation of vertically aligned carbon nanotubes directly grown on carbon nanofibers (VACNTs/CNFs) by combining electrospinning with pyrolysis technologies. The structure and morphology of VACNTs/CNFs could be precisely tuned and controlled by adjusting the percentage of reactants. The desired VACNTs/CNFs could not only possess high electric conductivity for efficient charge transport but could also increase surface area for accessing more electrolyte ions. When using an ionic liquid electrolyte, VACNTs/CNFs-based electric double layer (EDL) flexible supercapacitors can deliver a high specific energy of 70.7 Wh/kg at a current density of 0.5 A/g and at 30 degrees C, and an ultrahigh-energy density of 98.8 Wh/kg at a current density of 1.0 A/g and at 60 degrees C. Even after 20 000 charging/discharging cycles, the EDL capacitor still retains 97.0% of the initial capacitance. The excellent performance highlights the important role of the branched VACNTs in storing and accumulating charge and the CNF backbone in transporting charge, thereby boosting both power density and energy density.
收录类别SCI
语种英语
公开日期2016-05-03
内容类型期刊论文
源URL[http://ir.sinano.ac.cn/handle/332007/3426]  
专题苏州纳米技术与纳米仿生研究所_纳米研究国际实验室_张跃钢团队
推荐引用方式
GB/T 7714
Qiu, YC,Li, GZ,Hou, Y,et al. Vertically Aligned Carbon Nanotubes on Carbon Nanofibers: A Hierarchical Three-Dimensional Carbon Nanostructure for High-Energy Flexible Supercapacitors[J]. CHEMISTRY OF MATERIALS,2015,27(4):7.
APA Qiu, YC.,Li, GZ.,Hou, Y.,Pan, ZH.,Li, HF.,...&Zhang, YG.(2015).Vertically Aligned Carbon Nanotubes on Carbon Nanofibers: A Hierarchical Three-Dimensional Carbon Nanostructure for High-Energy Flexible Supercapacitors.CHEMISTRY OF MATERIALS,27(4),7.
MLA Qiu, YC,et al."Vertically Aligned Carbon Nanotubes on Carbon Nanofibers: A Hierarchical Three-Dimensional Carbon Nanostructure for High-Energy Flexible Supercapacitors".CHEMISTRY OF MATERIALS 27.4(2015):7.
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