MoSe2 porous microspheres comprising monolayer flakes with high electrocatalytic activity
Zhang, YJ(张叶俊); Gong, QF; Li, L(李轮); Yang, HC(杨红超); Li, YG; Wang, QB(王强斌)
刊名NANO RESEARCH
2015
卷号8期号:4页码:8
关键词MoSe2 transition-metal chalcogenides porous microspheres monolayer flakes electrocatalytic activity
通讯作者Wang, QB (王强斌)
英文摘要A facile colloidal route to synthesize MoSe2 porous microspheres with diameters of 400-600 nm made up of MoSe2 monolayer flakes (similar to 0.7 nm in thickness) is reported. The solvents trioctylamine (TOA) and oleylamine (OAM) are found to play important roles in the formation of MoSe2 microspheres, whereby TOA determines the three-dimensional (3D) microspherical morphology and OAM directs the formation of MoSe2 monolayer flakes. The robust 3D MoSe2 microspheres exhibit remarkable activity and durability for the electrocatalytic hydrogen evolution reaction (HER) in acid, maintaining a small onset overpotential of similar to 77 mV and keeping a small overpotential of 100 mV for a current density of 5 mA/cm(2) after 1,000 cycles. In addition, similar 3D WSe2 microspheres can also be prepared by using this method. We expect this facile colloidal route could further be expanded to synthesize other porous structures which will find applications in fields such as in energy storage, catalysis, and sensing.
收录类别SCI
语种英语
公开日期2016-05-03
内容类型期刊论文
源URL[http://ir.sinano.ac.cn/handle/332007/3396]  
专题苏州纳米技术与纳米仿生研究所_纳米生物医学与安全研究部_王强斌团队
推荐引用方式
GB/T 7714
Zhang, YJ,Gong, QF,Li, L,et al. MoSe2 porous microspheres comprising monolayer flakes with high electrocatalytic activity[J]. NANO RESEARCH,2015,8(4):8.
APA Zhang, YJ,Gong, QF,Li, L,Yang, HC,Li, YG,&Wang, QB.(2015).MoSe2 porous microspheres comprising monolayer flakes with high electrocatalytic activity.NANO RESEARCH,8(4),8.
MLA Zhang, YJ,et al."MoSe2 porous microspheres comprising monolayer flakes with high electrocatalytic activity".NANO RESEARCH 8.4(2015):8.
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