Mechanism of gold activation in supported gold catalysts for CO oxidation

	Mechanism of gold activation in supported gold catalysts for CO oxidation
	Hao, ZP; An, LD; Wang, HL; Hu, TD; Hu TD(胡天斗)
刊名	REACTION KINETICS AND CATALYSIS LETTERS
	2000
卷号	70 期号:1 页码:#REF!
关键词	mechanism of gold activation gold catalyst catalytic active center
通讯作者	Hao, ZP (reprint author), Chinese Acad Sci, Res Ctr Eco Environm Sci, Beijing 100085, Peoples R China.
英文摘要	Based on the structure characterization of Au/Fe2O3 catalysts, the mechanism of gold activation in supported gold catalysts was proposed as follow: Au3+ d(8) 6s(0) (catalyst precursor) (activation treatment)-->Audelta+ d(10-delta)6s(1) (catalyst) The possible catalytic active state is the partially oxidized gold (Audelta+) with unoccupied outer d orbitals, similar to the outer d orbital structure of Pt. Thus "inert" gold can become very active for CO oxidation.
学科主题	Chemistry
类目[WOS]	Chemistry, Physical
收录类别	SCI
WOS记录号	WOS:000088613100021
公开日期	2016-05-03
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/226537]
专题	高能物理研究所_多学科研究中心
推荐引用方式 GB/T 7714	Hao, ZP,An, LD,Wang, HL,et al. Mechanism of gold activation in supported gold catalysts for CO oxidation[J]. REACTION KINETICS AND CATALYSIS LETTERS,2000,70(1):#REF!.
APA	Hao, ZP,An, LD,Wang, HL,Hu, TD,&胡天斗.(2000).Mechanism of gold activation in supported gold catalysts for CO oxidation.REACTION KINETICS AND CATALYSIS LETTERS,70(1),#REF!.
MLA	Hao, ZP,et al."Mechanism of gold activation in supported gold catalysts for CO oxidation".REACTION KINETICS AND CATALYSIS LETTERS 70.1(2000):#REF!.