Multiple interactions on macroporous adsorption resins modified with ionic liquid
Wu XY(武晓玉)1,2,3; Liu Y(刘毅)1,2,4; Huo, Ting5; Chen, Zhenbin5; Liu YF(刘永峰)1,2,4; Di DL(邸多隆)1,2,4; Guo, Mei6; Zhao, Lei7; Di DL(邸多隆)
刊名Colloids and Surfaces A: Physicochemical and Engineering Aspects
2015
卷号487页码:35-41
关键词Macroporous adsorption resins Equilibrium isotherms Kinetics Dynamics Multiple interactions
ISSN号0927-7757
通讯作者邸多隆 ; Guo, Mei
英文摘要A comparative adsorption study was conducted on (−)-epigallocatechin gallate and (−)-epicatechin onto AB-8, chloromethyl/macroporous adsorption resin (chloromethyl/MAR), and ionic liquid/macroporous adsorption resin (ionic liquid/MAR) developed by our group. Equilibrium adsorption data showed that adsorption capacities of ionic liquid/MAR were superior to those of AB-8 and chloromethyl/MAR under the same conditions. Adsorption isotherms could be properly described by Langmuir isotherm, whereas adsorption kinetics curves obeyed pseudo-second-order model. Evaluated thermodynamic parameters revealed that adsorption was spontaneous and exothermic. The dynamic adsorption capacity of (−)-epigallocatechin gallate on ionic liquid/MAR at 298 K was approximately 72.5 mg/g dry resin. The resin column can be effectively regenerated using methanol. Analysis of adsorption mechanism suggested that it’s the large adsorption capacity was due to multiple adsorption interactions. Considering the excellent adsorption performance of ionic liquid/MAR, it has promising potential for the large-scale preliminary separation and purification of EGCG from tea extracts.
学科主题分析化学与药物化学
收录类别SCI
资助信息the National Natural Science Foundation of China (NSFC, no. 21374128);the “Hundred Talents Program” of the Chinese Academy of Sciences
语种英语
WOS记录号WOS:000365360000005
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/19103]  
专题兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
通讯作者Di DL(邸多隆)
作者单位1.Chinese Acad Sci, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Resource Chem & New Mat, Qingdao 266100, Peoples R China
5.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China
6.Gansu Coll Tradit Chinese Med, Dept Pharm, Lanzhou 730000, Peoples R China
7.Gansu Coll Tradit Chinese Med, Coll Gansu Prov, Key Lab Chem & Qual Tradit Chinese Med, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Wu XY,Liu Y,Huo, Ting,et al. Multiple interactions on macroporous adsorption resins modified with ionic liquid[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2015,487:35-41.
APA Wu XY.,Liu Y.,Huo, Ting.,Chen, Zhenbin.,Liu YF.,...&邸多隆.(2015).Multiple interactions on macroporous adsorption resins modified with ionic liquid.Colloids and Surfaces A: Physicochemical and Engineering Aspects,487,35-41.
MLA Wu XY,et al."Multiple interactions on macroporous adsorption resins modified with ionic liquid".Colloids and Surfaces A: Physicochemical and Engineering Aspects 487(2015):35-41.
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