Green synthesis of Pt-Au dendrimer-like nanoparticles supported on polydopamine-functionalized graphene and their high performance toward 4-nitrophenol reduction | |
Ye, Weichun1,2; Yu, Jing1; Zhou, Yaxin1; Gao, Daqiang2; Wang DA(王道爱)3; Wang, Chunming1; Xue, Desheng2 | |
刊名 | Applied Catalysis B: Environmental |
2016 | |
卷号 | 181页码:371-378 |
关键词 | Reduced graphene oxide Polydopamine Pt-Au alloy Dendrimer-like 4-Nitrophenol reduction |
ISSN号 | 0926-3373 |
通讯作者 | Ye, Weichun ; Xue, Desheng |
英文摘要 | A facile, environmentally friendly route is demonstrated for the synthesis of Pt-Au dendrimer-like nanoparticles on the surface of polydopamine (PDA)-wrapped reduced graphene oxide (RGO), in which Pt-Au alloy nanoparticles are synthesized by the reduction of H2PtCl6 and HAuCI4 with ascorbic acid. The effects of support material and chemical composition on the catalytic activity for the reduction of 4-nitrophenol (4-NP) are investigated in detail. Pt nanoparticles supported on PDA/RGO (Pt-PDA/RGO) exhibit significantly higher catalytic activity as compared to those exhibited by Pt nanop articles deposited on pristine graphene sheets (Pt-RGO) and commercial Pt/C catalyst. Furthermore, the chemical composition seriously affects the catalytic ability of the catalysts. With Pt-to-Au molar ratios of 3/1 and 1/1, significantly enhanced catalytic activities are observed, outperforming the support decorated with each single constituent. The high activity of Pt-Au-PDA/RGO can be explained by electronic effect involving in two types of electron transfers: (1) from the PDA coating to both Au and Pt atoms; (2) from Au to Pt atoms. Moreover, the Pt3Au1-PDA/RGO composite keeps a stable conversion efficiency of around 100% over six successive reduction reaction cycles. Through an experimental device of "filtering and catalyzing," the Pt3Aul- PDA/RGO sample exhibits superior efficiency for the purification of water containing 4-NP. Within 8 s, the water becomes colorless. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | the Fundamental Research Fund for the Central Universities (No. lzujbky-2014-69);the Post-Doctoral Science Foundation of China (No. 2013M542393) |
语种 | 英语 |
WOS记录号 | WOS:000364256000034 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/19069] |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.State Key Laboratory of Applied Organic Chemistry and Department of Chemistry, Lanzhou University, Lanzhou 730000, China 2.Key Laboratory for Magnetism and Magnetic Materials of MOE and Department of Physics, Lanzhou University, Lanzhou 730000, China 3.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
推荐引用方式 GB/T 7714 | Ye, Weichun,Yu, Jing,Zhou, Yaxin,et al. Green synthesis of Pt-Au dendrimer-like nanoparticles supported on polydopamine-functionalized graphene and their high performance toward 4-nitrophenol reduction[J]. Applied Catalysis B: Environmental,2016,181:371-378. |
APA | Ye, Weichun.,Yu, Jing.,Zhou, Yaxin.,Gao, Daqiang.,Wang DA.,...&Xue, Desheng.(2016).Green synthesis of Pt-Au dendrimer-like nanoparticles supported on polydopamine-functionalized graphene and their high performance toward 4-nitrophenol reduction.Applied Catalysis B: Environmental,181,371-378. |
MLA | Ye, Weichun,et al."Green synthesis of Pt-Au dendrimer-like nanoparticles supported on polydopamine-functionalized graphene and their high performance toward 4-nitrophenol reduction".Applied Catalysis B: Environmental 181(2016):371-378. |
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