Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates

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	Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates
	Zhao YW(赵应伟); Xie YJ(谢银君); Xia CG(夏春谷); Huang HM(黄汉民)
刊名	Advanced Synthesis and Catalysis
	2014
卷号	356 期号:11-12 页码:2471-2476
关键词	benzo[d][1 C-H activation palladium sulfuration thiocarbamates 3]oxathiol-2-ones
ISSN号	1615-4150
通讯作者	夏春谷 ; 黄汉民
英文摘要	A palladium-catalyzed intramolecular C-H bond sulfuration reaction of aryl thiocarbamates has been developed. This strategy provides a new route to benzo[d][1,3] oxathiol-2-ones with tolerance of a wide range of substituents. Mechanistic studies suggested that the C-H activation-sulfuration to afford 2-imino-1,3-benzoxathiole intermediate might involve an electrophilic palladation process.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (21203222;21133011;21173241)
语种	英语
WOS记录号	WOS:000340567100012
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/19256]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhao YW,Xie YJ,Xia CG,et al. Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates[J]. Advanced Synthesis and Catalysis,2014,356(11-12):2471-2476.
APA	Zhao YW,Xie YJ,Xia CG,&Huang HM.(2014).Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates.Advanced Synthesis and Catalysis,356(11-12),2471-2476.
MLA	Zhao YW,et al."Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates".Advanced Synthesis and Catalysis 356.11-12(2014):2471-2476.