Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene

	Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene
	Wang, Shengdong 1,2,3,4; Zhang, Wenjuan 1,2; Du, Shizhen 1,2; Asuha, Sin 3,4; Flisak, Zygmunt 1,2; Sun, Wen-Hua1,2
刊名	JOURNAL OF ORGANOMETALLIC CHEMISTRY
	2015-12-01
卷号	798 页码:408-413
关键词	2-propyl-4-arylimino-1 Nickel complex Ethylene oligomerization 3-dihydroacridine
英文摘要	Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel dihalide complexes were designed and prepared by metal-induced template reaction with NiCl2 center dot 6H(2)O or (DME)NiBr2. They were characterized by infrared spectroscopy and elemental analysis. Single crystal X-ray crystallography of representative complex Ni3 revealed a distorted trigonal bipyramidal geometry around nickel. The catalytic activities of the title nickel complexes were negatively affected by propyl substituent on their backbone when comparing with the results by unsubstituted ones. With the activation of diethylaluminium chloride, all nickel complexes exhibited moderate activity (up to 5.10 x 10(5) g mol(-1)(Ni) h(-1)) for ethylene oligomerization and oligomeric products ranged from C-4 to C-16. (C) 2015 Elsevier B.V. All rights reserved.
收录类别	SCI
语种	英语
公开日期	2016-01-19
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/29419]
专题	化学研究所_工程塑料实验室
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Inner Mongolia Normal Univ, Chem & Environm Sci Coll, Inner Mongolia 010022, Huhhot, Peoples R China 4.Key Lab Phys & Chem Funct Mat, Inner Mongolia 010022, Huhhot, Peoples R China
推荐引用方式 GB/T 7714	Wang, Shengdong,Zhang, Wenjuan,Du, Shizhen,et al. Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2015,798:408-413.
APA	Wang, Shengdong,Zhang, Wenjuan,Du, Shizhen,Asuha, Sin,Flisak, Zygmunt,&Sun, Wen-Hua.(2015).Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene.JOURNAL OF ORGANOMETALLIC CHEMISTRY,798,408-413.
MLA	Wang, Shengdong,et al."Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene".JOURNAL OF ORGANOMETALLIC CHEMISTRY 798(2015):408-413.