Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst

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	Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst
	Wang, Hong-Yan 1,2; Jiao, Tian-Tian 2; Li, Zeng-Xi 1; Li, Chun-Shan 2; Zhang, Suo-Jiang 2; Zhang, Jian-Ling 3
刊名	FUEL PROCESSING TECHNOLOGY
	2015-11-01
卷号	139 期号:NOV 页码:91-99
关键词	Hydrogenation Palm oil Biodiesel Cetane number
ISSN号	0378-3820
英文摘要	Biodiesel, derived from vegetable oil via hydrotreating, is becoming a promising alternative energy. Novel Ni-Mo-W/gamma-Al2O3-ZSM-5 catalysts were developed and firstly applied in palm oil hydrogenation process. The catalysts were prepared by extrusion method and characterized by XRD, SEM, TEM, BET, NH3-TPD, and H-2-TPR The influences of acidity on the activity, selectivity, and stability of catalysts were systematically studied. The mechanisms of deoxygenation and isomerization were discussed. The catalyst Ni-Mo-W (5 wt.%-5 wt.%-15 wt.%)/gamma-Al2O3-ZSM-5 (85 wt.% 15 wt.%) was confirmed as the optimum one. Finally, the key reaction parameters such as reaction temperature, pressure, liquid hourly space velocity and H-2/oil volume ratio were optimized. The hydrogenation reaction path of palm oil was also proposed. (C) 2015 Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical
研究领域[WOS]	Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]	SUPPORTED NICKEL-CATALYSTS ; BIODIESEL PRODUCTION ; VEGETABLE-OILS ; JATROPHA OIL ; SOYBEAN OIL ; COAL-TAR ; HYDRODEOXYGENATION ; DEOXYGENATION ; TRIGLYCERIDES ; DIESEL
收录类别	SCI
语种	英语
WOS记录号	WOS:000362619200012
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/19614]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Hong-Yan,Jiao, Tian-Tian,Li, Zeng-Xi,et al. Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst[J]. FUEL PROCESSING TECHNOLOGY,2015,139(NOV):91-99.
APA	Wang, Hong-Yan,Jiao, Tian-Tian,Li, Zeng-Xi,Li, Chun-Shan,Zhang, Suo-Jiang,&Zhang, Jian-Ling.(2015).Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst.FUEL PROCESSING TECHNOLOGY,139(NOV),91-99.
MLA	Wang, Hong-Yan,et al."Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst".FUEL PROCESSING TECHNOLOGY 139.NOV(2015):91-99.