Mechanism of Hg-0 oxidation in the presence of HCl over a commercial V2O5-WO3/TiO2 SCR catalyst | |
Liu, Ruihui1,2; Xu, Wenqing1; Tong, Li1; Zhu, Tingyu1 | |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA |
2015-10-01 | |
卷号 | 36期号:OCT页码:76-83 |
关键词 | Mercury Hydrogen chloride Vanadium-based catalyst Oxidation Mechanism |
ISSN号 | 1001-0742 |
英文摘要 | Experiments were conducted in a fixed-bed reactor containing a commercial V2O5/WO3/TiO2 catalyst to investigatemercury oxidation in the presence of HCl and O-2. Mercury oxidation was improved significantly in the presence of HCl and O-2, and the Hg-0 oxidation efficiencies decreased slowly as the temperature increased from 200 to 400 degrees C. Upon pretreatment with HCl and O-2 at 350 degrees C, the catalyst demonstrated higher catalytic activity for Hg-0 oxidation. Notably, the effect of pretreatment with HCl alone was not obvious. For the catalyst treated with HCl and O-2, better performance was observed with lower reaction temperatures. The results showed that both HCl and Hg-0 were first adsorbed onto the catalyst and then reacted with O-2 following its adsorption, which indicates that the oxidation of Hg0 over the commercial catalyst followed the Langmuir-Hinshelwood mechanism. Several characterization techniques, including Hg-0 temperature-programmed desorption (Hg-TPD) and X-ray photoelectron spectroscopy (XPS), were employed in this work. Hg-TPD profiles showed that weakly adsorbed mercury species were converted to strongly bound species in the presence of HCl and O-2. XPS patterns indicated that new chemisorbed oxygen species were formed by the adsorption of HCl, which consequently facilitated the oxidation of mercury. (C) 2015 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. |
WOS标题词 | Science & Technology ; Life Sciences & Biomedicine |
类目[WOS] | Environmental Sciences |
研究领域[WOS] | Environmental Sciences & Ecology |
关键词[WOS] | COMBUSTION FLUE-GAS ; PHASE ELEMENTAL MERCURY ; IRON-BASED SORBENTS ; ACTIVATED CARBON ; FUEL GAS ; REDUCTION CATALYSTS ; HYDROCHLORIC-ACID ; POWER-PLANTS ; REMOVAL ; TEMPERATURE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000362983500010 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/19666] |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China 2.Northeastern Univ, Qinhuangdao Branch, Sch Resources & Mat, Qinhuangdao 066004, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Ruihui,Xu, Wenqing,Tong, Li,et al. Mechanism of Hg-0 oxidation in the presence of HCl over a commercial V2O5-WO3/TiO2 SCR catalyst[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2015,36(OCT):76-83. |
APA | Liu, Ruihui,Xu, Wenqing,Tong, Li,&Zhu, Tingyu.(2015).Mechanism of Hg-0 oxidation in the presence of HCl over a commercial V2O5-WO3/TiO2 SCR catalyst.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,36(OCT),76-83. |
MLA | Liu, Ruihui,et al."Mechanism of Hg-0 oxidation in the presence of HCl over a commercial V2O5-WO3/TiO2 SCR catalyst".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 36.OCT(2015):76-83. |
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