Heteropolyacids as Efficient Catalysts for the Synthesis of Precursors to Ethylene Glycol by the Liquid-phase Carbonylation of Dimethoxymethane

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	Heteropolyacids as Efficient Catalysts for the Synthesis of Precursors to Ethylene Glycol by the Liquid-phase Carbonylation of Dimethoxymethane
	Wang JP(王军鹏)1,2 ; Liu JH(刘建华)1 ; Song HY(宋河远)1 ; Chen J(陈静)1 ; Chen J(陈静); Chen J(陈静)
刊名	Chemistry Letters
	2015
卷号	44 期号:6 页码:806-808
ISSN号	0366-7022
通讯作者	陈静
英文摘要	Methyl methoxyacetate (MMAc), a precursor to ethylene glycol (EG), was synthesized successfully via the liquid-phase carbonylation of dimethoxymethane (DMM) catalyzed by heteropolyacids (HPAs). The experiment results showed that H₃PW₁₂O₄₀ (PW₁₂) exhibited the best catalytic performance for the carbonylation of DMM, and its high catalytic activity was attributed to the synergistic effect between its superior acidic strength and the high polarity of the solvent.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (Nos. 21373248;21133011)
语种	英语
WOS记录号	WOS:000355786600026
公开日期	2015-12-24
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18470]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Chen J(陈静); Chen J(陈静)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang JP,Liu JH,Song HY,et al. Heteropolyacids as Efficient Catalysts for the Synthesis of Precursors to Ethylene Glycol by the Liquid-phase Carbonylation of Dimethoxymethane[J]. Chemistry Letters,2015,44(6):806-808.
APA	Wang JP,Liu JH,Song HY,Chen J,陈静,&陈静.(2015).Heteropolyacids as Efficient Catalysts for the Synthesis of Precursors to Ethylene Glycol by the Liquid-phase Carbonylation of Dimethoxymethane.Chemistry Letters,44(6),806-808.
MLA	Wang JP,et al."Heteropolyacids as Efficient Catalysts for the Synthesis of Precursors to Ethylene Glycol by the Liquid-phase Carbonylation of Dimethoxymethane".Chemistry Letters 44.6(2015):806-808.