Effects of different anionic surfactants on methane hydrate formation
Wang, Fei1,2; Jia, Zhen-Zhen3; Luo, Sheng-Jun1; Fu, Shan-Fei1,2; Wang, Lin1; Shi, Xiao-Shuang1; Wang, Chuan-Shui1; Guo, Rong-Bo1
刊名CHEMICAL ENGINEERING SCIENCE
2015-12-01
卷号137页码:896-903
关键词Methane hydrates Anionic surfactants Induction time Contact angle Hydrate growth
英文摘要In this work, the effects of anionic surfactants on methane hydrate formation were studied. For comparison, three anionic surfactants with the same carbon chain but different head groups, sodium dodecyl sulfonate (SDSN), sodium dodecyl sulfate (SDS) and sodium dodecyl benzene sulfonate (SDBS) were used. SOBS was detected to form micelles under hydrate formation conditions, while SDSN and SDS precipitated before micelles were formed. As a result, concentrations of SDSN and SOS did not show obvious influence on the promotion effect to methane hydrate formation, while the concentration of SOBS significantly affected the promotion effect because of the micelle effect. When SDSN and SDS were used hydrates grew upwards on the reactor wall due to the relatively narrow contact angle of the surfactant solutions on the reactor sidewall, while SDBS led to the hydrates formed mainly in the bottom of the reactor as a result of the relatively wide contact angle. In addition, SDSN and SDS led to much higher growth rate in comparison to SOBS due to the upward growth of hydrates on the reactor sidewall. (C) 2015 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Technology
类目[WOS]Engineering, Chemical
研究领域[WOS]Engineering
关键词[WOS]SODIUM DODECYL-SULFATE ; UNSTIRRED GAS/LIQUID SYSTEM ; GAS HYDRATE ; AMBIENT-TEMPERATURE ; FORMING CONDITIONS ; FORMATION KINETICS ; AQUEOUS-SOLUTION ; ALKYL SULFATES ; STORAGE ; SOLUBILITY
收录类别SCI
语种英语
WOS记录号WOS:000361772400082
公开日期2015-12-24
内容类型期刊论文
源URL[http://ir.qibebt.ac.cn/handle/337004/6602]  
专题青岛生物能源与过程研究所_生物制氢与沼气团队
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Shandong Ind Engn Lab Biogas Prod & Utilizat, Qingdao 266101, Shandong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Guizhou Univ, Guiyang 550025, Peoples R China
推荐引用方式
GB/T 7714
Wang, Fei,Jia, Zhen-Zhen,Luo, Sheng-Jun,et al. Effects of different anionic surfactants on methane hydrate formation[J]. CHEMICAL ENGINEERING SCIENCE,2015,137:896-903.
APA Wang, Fei.,Jia, Zhen-Zhen.,Luo, Sheng-Jun.,Fu, Shan-Fei.,Wang, Lin.,...&Guo, Rong-Bo.(2015).Effects of different anionic surfactants on methane hydrate formation.CHEMICAL ENGINEERING SCIENCE,137,896-903.
MLA Wang, Fei,et al."Effects of different anionic surfactants on methane hydrate formation".CHEMICAL ENGINEERING SCIENCE 137(2015):896-903.
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