Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 储氢及新型纳孔材料团队

	Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions
	Lv, Xiaoxia 1; Li, Liangjun 1; Sun, Xiaoming 2; Zhang, Hongyu 2; Cai, Jinjun 1; Wang, Chao 1; Tang, Sifu 1; Zhao, Xuebo 1
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2014-03-01
卷号	9 期号:3 页码:901-907
关键词	coordination polymers diphosphonate ligand hysteresis sorption pi interactions polymers
英文摘要	The microporous coordination polymer [Co(H2L)(bipy)(0.5)]2H(2)O (1, bipy=4,4-bipyridine) was synthesized on the basis of the V-shaped flexible diphosphonate ligand (2,4,6-trimethyl-1,3-phenylene)bis(methylene)diphosphonic acid (H4L) and the auxiliary bipy ligand under hydrothermal conditions. The structure of this compound was characterized by single-crystal X-ray diffraction. By joining the diphosphonate ligands and bipy through tetrahedral [CoO3N] clusters, a 2D square grid layered network was formed. Further stacking of these layers on the basis of - interactions resulted in a pseudo-3D microporous network with 1D channels running through the a axis. Gas sorption studies for CO2, H-2, CH4, N-2, and O-2 on this coordination polymer were performed, and the results revealed interesting dynamic and hysteresis sorption behavior toward H-2 at low temperature.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	METAL-ORGANIC FRAMEWORKS ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; BUILDING-BLOCKS ; ADSORPTION PROPERTIES ; SELECTIVE ADSORPTION ; MAGNETIC-PROPERTIES ; BRIDGING-LIGAND ; HYDROGEN ; CO2 ; TRANSFORMATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000331611900030
公开日期	2015-12-24
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/6154]
专题	青岛生物能源与过程研究所_储氢及新型纳孔材料团队
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Lab Hydrogen Storage & Novel Nanoporous Mat, Qingdao 266101, Peoples R China 2.China Univ Petr, Sch Chem Engn, State Key Lab Heavy Oil, Qingdao 266555, Peoples R China
推荐引用方式 GB/T 7714	Lv, Xiaoxia,Li, Liangjun,Sun, Xiaoming,et al. Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions[J]. CHEMISTRY-AN ASIAN JOURNAL,2014,9(3):901-907.
APA	Lv, Xiaoxia.,Li, Liangjun.,Sun, Xiaoming.,Zhang, Hongyu.,Cai, Jinjun.,...&Zhao, Xuebo.(2014).Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions.CHEMISTRY-AN ASIAN JOURNAL,9(3),901-907.
MLA	Lv, Xiaoxia,et al."Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions".CHEMISTRY-AN ASIAN JOURNAL 9.3(2014):901-907.