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	Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition
	Chen, Gang; Yang, Jing; Gao, Suo; Zhang, Yu; Hao, Xiaojiang
刊名	RESEARCH ON CHEMICAL INTERMEDIATES
	2015-07-01
卷号	41期号:7页码:4987-4996
关键词	Regioselectivity Theoretical Spiro-oxindole [3+2] Cycloaddition
英文摘要	Study of the structures of a series of spiro [pyrrolidine-2,3'-oxindole] derivatives synthesized by [3+2] cycloaddition reaction of isatin, alpha-amino acids, and beta-substituted phenylethylenes revealed the regioselectivity of the reaction was completely novel. The reaction mechanism for [3+2] cycloaddition of oxindole azomethine ylide and the beta-substituted phenylethylenes was calculated by use of density functional theory with the B3LYP functional and different basis sets. The results show that the regioselectivity of this [3+2] cycloaddition reaction is kinetically controlled, which agrees with experimental results.
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	1,3-DIPOLAR CYCLOADDITION ; DERIVATIVES
收录类别	SCI
语种	英语
WOS记录号	WOS:000356608700072
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/24975]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
推荐引用方式 GB/T 7714	Chen, Gang,Yang, Jing,Gao, Suo,et al. Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2015,41(7):4987-4996.
APA	Chen, Gang,Yang, Jing,Gao, Suo,Zhang, Yu,&Hao, Xiaojiang.(2015).Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition.RESEARCH ON CHEMICAL INTERMEDIATES,41(7),4987-4996.
MLA	Chen, Gang,et al."Theoretical study of regioselectivity in the synthesis of spiro [pyrrolidine-2,3'-oxindole] compounds by [3+2] cycloaddition".RESEARCH ON CHEMICAL INTERMEDIATES 41.7(2015):4987-4996.

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